Volume-demanding cis-trans isomerization of 1,2-diaryl olefins in the solid state

Arunkumar Natarajan, Joel T. Mague, K. Venkatesan, T. Arai, Vaidhyanathan Ramamurthy

Research output: Contribution to journalArticle

39 Citations (Scopus)

Abstract

Volume-demanding cis-trans photoisomerization of the aromatic substituted alkenes 1-3 in the solid state at room temperature and at 50 °C is presented. Alkene 3 did not undergo the cis-trans isomerization in the solid state either at room temperature or at 50 °C. The importance of the presence of void space near the reaction center to facilitate the large volume change during cis-trans photoisomerization is discussed.

Original languageEnglish
Pages (from-to)1055-1059
Number of pages5
JournalJournal of Organic Chemistry
Volume71
Issue number3
DOIs
StatePublished - Feb 3 2006

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Photoisomerization
Alkenes
Isomerization
Temperature

ASJC Scopus subject areas

  • Organic Chemistry

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Volume-demanding cis-trans isomerization of 1,2-diaryl olefins in the solid state. / Natarajan, Arunkumar; Mague, Joel T.; Venkatesan, K.; Arai, T.; Ramamurthy, Vaidhyanathan.

In: Journal of Organic Chemistry, Vol. 71, No. 3, 03.02.2006, p. 1055-1059.

Research output: Contribution to journalArticle

Natarajan, Arunkumar ; Mague, Joel T. ; Venkatesan, K. ; Arai, T. ; Ramamurthy, Vaidhyanathan. / Volume-demanding cis-trans isomerization of 1,2-diaryl olefins in the solid state. In: Journal of Organic Chemistry. 2006 ; Vol. 71, No. 3. pp. 1055-1059.
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