Abstract
1,5-Di(4,5-disubstituted-2-aminophenyl) penta-1,5-diaza-1,3- dienatonickel(II) chlorides are reacted with formaldehyde and barbituric acid in the presence of catalytic amount of perchloric acid to synthesize two members of a new type of aza macrocyclic complex of Ni(II) . The macrocyclic complexes, which are diamagnetic, have been characterised by conductivity, electronic spectra, thermal analysis and NMR (1H and 13C) spectroscopy. The structure of the cation in one of the macrocyclic complexes has been examined by using molecular mechanics.
| Original language | English |
|---|---|
| Pages (from-to) | 985-990 |
| Number of pages | 6 |
| Journal | Indian Journal of Chemistry - Section A Inorganic, Physical, Theoretical and Analytical Chemistry |
| Volume | 38 |
| Issue number | 10 |
| State | Published - Oct 1 1999 |
| Externally published | Yes |
Fingerprint
ASJC Scopus subject areas
- Chemistry(all)
Cite this
Use of barbituric acid as a 'padlock' to generate azamacrocyclic complexes of Ni(II) containing fused aromatic rings. / Lewis, Nita; Patra, Goutam K.; Hati, Sanchita; Datta, Dipankar.
In: Indian Journal of Chemistry - Section A Inorganic, Physical, Theoretical and Analytical Chemistry, Vol. 38, No. 10, 01.10.1999, p. 985-990.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Use of barbituric acid as a 'padlock' to generate azamacrocyclic complexes of Ni(II) containing fused aromatic rings
AU - Lewis, Nita
AU - Patra, Goutam K.
AU - Hati, Sanchita
AU - Datta, Dipankar
PY - 1999/10/1
Y1 - 1999/10/1
N2 - 1,5-Di(4,5-disubstituted-2-aminophenyl) penta-1,5-diaza-1,3- dienatonickel(II) chlorides are reacted with formaldehyde and barbituric acid in the presence of catalytic amount of perchloric acid to synthesize two members of a new type of aza macrocyclic complex of Ni(II) . The macrocyclic complexes, which are diamagnetic, have been characterised by conductivity, electronic spectra, thermal analysis and NMR (1H and 13C) spectroscopy. The structure of the cation in one of the macrocyclic complexes has been examined by using molecular mechanics.
AB - 1,5-Di(4,5-disubstituted-2-aminophenyl) penta-1,5-diaza-1,3- dienatonickel(II) chlorides are reacted with formaldehyde and barbituric acid in the presence of catalytic amount of perchloric acid to synthesize two members of a new type of aza macrocyclic complex of Ni(II) . The macrocyclic complexes, which are diamagnetic, have been characterised by conductivity, electronic spectra, thermal analysis and NMR (1H and 13C) spectroscopy. The structure of the cation in one of the macrocyclic complexes has been examined by using molecular mechanics.
UR - http://www.scopus.com/inward/record.url?scp=0033492578&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0033492578&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:0033492578
VL - 38
SP - 985
EP - 990
JO - Indian Journal of Chemistry - Section A Inorganic, Physical, Theoretical and Analytical Chemistry
JF - Indian Journal of Chemistry - Section A Inorganic, Physical, Theoretical and Analytical Chemistry
SN - 0376-4710
IS - 10
ER -