Use of Airborne In Situ VOC Measurements to Estimate Transit Time Spectrum

An Observation-Based Diagnostic of Convective Transport

Zhengzhao Johnny Luo, Laura L. Pan, Elliot L Atlas, Sofia M. Chelpon, Shawn B. Honomichl, Eric C. Apel, Rebecca S. Hornbrook, Samuel R. Hall

Research output: Contribution to journalArticle

Abstract

Convective transport from the marine boundary layer to the upper troposphere (UT) is investigated using airborne in situ measurements of chemical species over the tropical western Pacific. Using 42 volatile organic compounds with photochemical lifetimes ranging from shorter than a day to multiple decades, we derive a transit time spectrum G(t) and the associated modal and mean transit times for the UT air mass over the convectively dominant tropical western Pacific region. G(t) describes relative contributions of air masses transported from the marine boundary layer to the UT via all transport paths with different transit times. We further demonstrate that the volatile organic compound-derived transit time scale is broadly comparable to that estimated from convective mass flux. The observation-based transit time spectrum not only provides insights into convective transport pathways, but also has the potential to serve as an effective diagnostic for evaluating the representation of convective transport in global models.

Original languageEnglish (US)
Pages (from-to)13,150-13,157
JournalGeophysical Research Letters
Volume45
Issue number23
DOIs
StatePublished - Dec 16 2018

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volatile organic compounds
transit time
volatile organic compound
troposphere
estimates
air mass
air masses
boundary layer
boundary layers
in situ measurement
timescale
in situ
life (durability)

ASJC Scopus subject areas

  • Geophysics
  • Earth and Planetary Sciences(all)

Cite this

Use of Airborne In Situ VOC Measurements to Estimate Transit Time Spectrum : An Observation-Based Diagnostic of Convective Transport. / Luo, Zhengzhao Johnny; Pan, Laura L.; Atlas, Elliot L; Chelpon, Sofia M.; Honomichl, Shawn B.; Apel, Eric C.; Hornbrook, Rebecca S.; Hall, Samuel R.

In: Geophysical Research Letters, Vol. 45, No. 23, 16.12.2018, p. 13,150-13,157.

Research output: Contribution to journalArticle

Luo, Zhengzhao Johnny ; Pan, Laura L. ; Atlas, Elliot L ; Chelpon, Sofia M. ; Honomichl, Shawn B. ; Apel, Eric C. ; Hornbrook, Rebecca S. ; Hall, Samuel R. / Use of Airborne In Situ VOC Measurements to Estimate Transit Time Spectrum : An Observation-Based Diagnostic of Convective Transport. In: Geophysical Research Letters. 2018 ; Vol. 45, No. 23. pp. 13,150-13,157.
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