Use of a confined space (zeolite) in enantio- and diastereo-selective photoreactions

J. Shailaja; J. Sivaguru; Sundararajan Uppili; Abraham Joy; V. Ramamurthy

doi:10.1016/S1387-1811(01)00348-1

Use of a confined space (zeolite) in enantio- and diastereo-selective photoreactions

J. Shailaja, J. Sivaguru, Sundararajan Uppili, Abraham Joy, V. Ramamurthy

Research output: Contribution to journal › Article › peer-review

18 Scopus citations

Abstract

The confined spaces of zeolites have been found to be ideal for carrying out enantio- and diastereo-selective photoreactions. Four methods, (chiral inductor, chiral auxiliary, a combination (chiral inductor + chiral auxiliary) and chiral inductor as a reagent) have been explored and all were found to give reasonable chiral induction on several systems. The uniqueness of zeolites as media although established in this study, the factors that control the high chiral induction in zeolite with respect to solution are yet to be established.

Original language	English (US)
Pages (from-to)	319-328
Number of pages	10
Journal	Microporous and Mesoporous Materials
Volume	48
Issue number	1-3
DOIs	https://doi.org/10.1016/S1387-1811(01)00348-1
State	Published - Nov 2001
Externally published	Yes

Keywords

Chiral induction
Enantioselectivity
Photoreactions
Zeolite

ASJC Scopus subject areas

Catalysis
Materials Science(all)

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10.1016/S1387-1811(01)00348-1

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abstract = "The confined spaces of zeolites have been found to be ideal for carrying out enantio- and diastereo-selective photoreactions. Four methods, (chiral inductor, chiral auxiliary, a combination (chiral inductor + chiral auxiliary) and chiral inductor as a reagent) have been explored and all were found to give reasonable chiral induction on several systems. The uniqueness of zeolites as media although established in this study, the factors that control the high chiral induction in zeolite with respect to solution are yet to be established.",

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AU - Sivaguru, J.

AU - Uppili, Sundararajan

AU - Joy, Abraham

AU - Ramamurthy, V.

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AB - The confined spaces of zeolites have been found to be ideal for carrying out enantio- and diastereo-selective photoreactions. Four methods, (chiral inductor, chiral auxiliary, a combination (chiral inductor + chiral auxiliary) and chiral inductor as a reagent) have been explored and all were found to give reasonable chiral induction on several systems. The uniqueness of zeolites as media although established in this study, the factors that control the high chiral induction in zeolite with respect to solution are yet to be established.

KW - Chiral induction

KW - Enantioselectivity

KW - Photoreactions

KW - Zeolite

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