Abstract
The confined spaces of zeolites have been found to be ideal for carrying out enantio- and diastereo-selective photoreactions. Four methods, (chiral inductor, chiral auxiliary, a combination (chiral inductor + chiral auxiliary) and chiral inductor as a reagent) have been explored and all were found to give reasonable chiral induction on several systems. The uniqueness of zeolites as media although established in this study, the factors that control the high chiral induction in zeolite with respect to solution are yet to be established.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 319-328 |
| Number of pages | 10 |
| Journal | Microporous and Mesoporous Materials |
| Volume | 48 |
| Issue number | 1-3 |
| DOIs | |
| State | Published - Nov 1 2001 |
| Externally published | Yes |
Keywords
- Chiral induction
- Enantioselectivity
- Photoreactions
- Zeolite
ASJC Scopus subject areas
- Catalysis
- Materials Science(all)
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Cite this
Shailaja, J., Sivaguru, J., Uppili, S., Joy, A., & Ramamurthy, V. (2001). Use of a confined space (zeolite) in enantio- and diastereo-selective photoreactions. Microporous and Mesoporous Materials, 48(1-3), 319-328. https://doi.org/10.1016/S1387-1811(01)00348-1