Two phase flow study in a direct methanol fuel cell

Jiabin Ge, Hongtan Liu

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

A three dimensional, two-phase, multi-component model has been developed for a liquid-fed DMFC. Both liquid and gas phases are considered in the entire anode, including the channel, the diffusion layer and the catalyst layer; while at the cathode, two-phases are considered in the gas diffusion layer and the catalyst layer but single gas phase is considered in the channel. For the electrochemical kinetics, the Tafel equation incorporating the effects of two phases is used at both the cathode and anode sides. At the anode side, the presence of gas phase reduces the active catalyst areas; at the cathode side, the presence of liquid reduces the active catalyst areas. The mixed potential effects due to methanol crossover are also included in the model. The modeling results showed that the porosity of the anode diffusion layer played a very important role in the DMFC performance. With a low porosity, the produced carbon dioxide cannot be removed effectively from the catalyst layer, thus reducing the active catalyst area as well as blocking methanol from reaching the reaction zone. A similar effect exits in the cathode for the liquid water. The modeling results also show that the single-phase flow models over-predict methanol cross-over.

Original languageEnglish (US)
Title of host publicationAmerican Society of Mechanical Engineers, Advanced Energy Systems Division (Publication) AES
Pages309-317
Number of pages9
Volume45
DOIs
StatePublished - 2005
Event2005 ASME International Mechanical Engineering Congress and Exposition, IMECE - Orlando, FL, United States
Duration: Nov 5 2005Nov 11 2005

Other

Other2005 ASME International Mechanical Engineering Congress and Exposition, IMECE
CountryUnited States
CityOrlando, FL
Period11/5/0511/11/05

Fingerprint

Direct methanol fuel cells (DMFC)
Two phase flow
Catalysts
Anodes
Cathodes
Methanol
Liquids
Porosity
Gases
Diffusion in gases
Carbon dioxide
Kinetics
Water

ASJC Scopus subject areas

  • Mechanical Engineering
  • Energy Engineering and Power Technology

Cite this

Ge, J., & Liu, H. (2005). Two phase flow study in a direct methanol fuel cell. In American Society of Mechanical Engineers, Advanced Energy Systems Division (Publication) AES (Vol. 45, pp. 309-317) https://doi.org/10.1115/IMECE2005-80241

Two phase flow study in a direct methanol fuel cell. / Ge, Jiabin; Liu, Hongtan.

American Society of Mechanical Engineers, Advanced Energy Systems Division (Publication) AES. Vol. 45 2005. p. 309-317.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Ge, J & Liu, H 2005, Two phase flow study in a direct methanol fuel cell. in American Society of Mechanical Engineers, Advanced Energy Systems Division (Publication) AES. vol. 45, pp. 309-317, 2005 ASME International Mechanical Engineering Congress and Exposition, IMECE, Orlando, FL, United States, 11/5/05. https://doi.org/10.1115/IMECE2005-80241
Ge J, Liu H. Two phase flow study in a direct methanol fuel cell. In American Society of Mechanical Engineers, Advanced Energy Systems Division (Publication) AES. Vol. 45. 2005. p. 309-317 https://doi.org/10.1115/IMECE2005-80241
Ge, Jiabin ; Liu, Hongtan. / Two phase flow study in a direct methanol fuel cell. American Society of Mechanical Engineers, Advanced Energy Systems Division (Publication) AES. Vol. 45 2005. pp. 309-317
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