Tropospheric hydroxyl and atomic chlorine concentrations, and mixing timescales determined from hydrocarbon and halocarbon measurements made over the Southern Ocean

Oliver W. Wingenter, Donald R. Blake, Nicola J. Blake, Barkley C. Sive, F. Sherwood Rowland, Elliot L Atlas, Frank Flocke

Research output: Contribution to journalArticle

102 Citations (Scopus)

Abstract

During the First Aerosol Characterization Experiment (ACE 1) field campaign, 1419 whole air samples were collected over the Southern Ocean, of which approximately 700 samples were collected in the marine boundary layer (MBL), 300 samples were taken in the free troposphere (FT), and the remainder were collected in the buffer layer (BuL), the layer between the MBL and FT. Concentrations of tetrachloroethene, ethane, ethyne, and propane decayed over the 24 day duration of the intensive portion of the field campaign, which began November 18, 1995. This decline was consistent with what is known about seasonal increase of HO and the seasonal decrease in biomass burning. Using a simple empirical model, the best fit to the observations was obtained when the average [HO] was 6.1 ± 0.3 × 105 HO cm-3, and an average [Cl] of 720 ± 100 Cl cm-3. The corresponding exchange times were 14 ± 2 days between the MBL and FT, and 49 +40/-13 days between the MBL in the intensive campaign region and the MBL region to the north (nMBL).

Original languageEnglish (US)
Article number1999JD900203
Pages (from-to)21819-21828
Number of pages10
JournalJournal of Geophysical Research C: Oceans
Volume104
Issue numberD17
StatePublished - Sep 20 1999
Externally publishedYes

Fingerprint

Halocarbons
halocarbons
halocarbon
Chlorine
Hydrocarbons
Hydroxyl Radical
chlorine
boundary layers
oceans
Boundary layers
hydrocarbons
boundary layer
Troposphere
hydrocarbon
timescale
troposphere
ocean
ACE 1
Tetrachloroethylene
Acetylene

ASJC Scopus subject areas

  • Geochemistry and Petrology
  • Geophysics
  • Earth and Planetary Sciences (miscellaneous)
  • Space and Planetary Science
  • Atmospheric Science
  • Astronomy and Astrophysics
  • Oceanography

Cite this

Tropospheric hydroxyl and atomic chlorine concentrations, and mixing timescales determined from hydrocarbon and halocarbon measurements made over the Southern Ocean. / Wingenter, Oliver W.; Blake, Donald R.; Blake, Nicola J.; Sive, Barkley C.; Rowland, F. Sherwood; Atlas, Elliot L; Flocke, Frank.

In: Journal of Geophysical Research C: Oceans, Vol. 104, No. D17, 1999JD900203, 20.09.1999, p. 21819-21828.

Research output: Contribution to journalArticle

Wingenter, Oliver W. ; Blake, Donald R. ; Blake, Nicola J. ; Sive, Barkley C. ; Rowland, F. Sherwood ; Atlas, Elliot L ; Flocke, Frank. / Tropospheric hydroxyl and atomic chlorine concentrations, and mixing timescales determined from hydrocarbon and halocarbon measurements made over the Southern Ocean. In: Journal of Geophysical Research C: Oceans. 1999 ; Vol. 104, No. D17. pp. 21819-21828.
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