Toward less dependence on platinum group metal catalysts: The merits of utilizing tin

Richard D. Adams; Douglas A. Blom; Burjor Captain; Robert Raja; John Meurig Thomas; Eszter Trufan

doi:10.1021/la801759d

Toward less dependence on platinum group metal catalysts: The merits of utilizing tin

Richard D. Adams, Douglas A. Blom, Burjor Captain, Robert Raja, John Meurig Thomas, Eszter Trufan

Chemistry

Research output: Contribution to journal › Article › peer-review

62 Scopus citations

Abstract

Minute stoichiometric bimetallic clusters rich in tin (PtSn₂, RhSn₂, and RuSn₂) are powerful selective hydrogénation catalysts: these "molecular metallic" entities, supported on mesoporous silica and characterized by aberration-corrected electron microscopy, yield high percentages of cyclododecene (CDE) at fractional conversions ranging from 0.45 to 0.70 of the parent cyclododecatriene (CDT) at modest temperatures and under solvent-free conditions.

Original language	English (US)
Pages (from-to)	9223-9226
Number of pages	4
Journal	Langmuir
Volume	24
Issue number	17
DOIs	https://doi.org/10.1021/la801759d
State	Published - Sep 2 2008

ASJC Scopus subject areas

Materials Science(all)
Condensed Matter Physics
Surfaces and Interfaces
Spectroscopy
Electrochemistry

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AU - Blom, Douglas A.

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AU - Raja, Robert

AU - Thomas, John Meurig

AU - Trufan, Eszter

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AB - Minute stoichiometric bimetallic clusters rich in tin (PtSn2, RhSn2, and RuSn2) are powerful selective hydrogénation catalysts: these "molecular metallic" entities, supported on mesoporous silica and characterized by aberration-corrected electron microscopy, yield high percentages of cyclododecene (CDE) at fractional conversions ranging from 0.45 to 0.70 of the parent cyclododecatriene (CDT) at modest temperatures and under solvent-free conditions.

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Toward less dependence on platinum group metal catalysts: The merits of utilizing tin

Abstract

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