Thermodynamics of Ionization of Aqueous Methoxy Phenols

Frank J. Mulero, J. C. Ahluwalia, Loren G. Helper

Research output: Contribution to journalArticle

6 Scopus citations

Abstract

Heats of ionization of o-methoxy phenol, m-methoxy phenol and p-methoxy phenol in aqueous solution have been determined calorimetrically. Combination of our results with ΔF° values from ionization constants gives °S° values for ionization of these substituted phenols in aqueous solution. Interpretation of the thermodynamic data in terms of resonance and inductive effects and solute-solvent interactions is discussed briefly.

Original languageEnglish (US)
Pages (from-to)192-193
Number of pages2
JournalJournal of Chemical and Engineering Data
Volume9
Issue number2
DOIs
StatePublished - Apr 1 1964

ASJC Scopus subject areas

  • Chemistry(all)
  • Chemical Engineering(all)

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