Thermodynamics of Ionization of Aqueous Methoxy Phenols

Frank J. Mulero; J. C. Ahluwalia; Loren G. Helper

doi:10.1021/je60021a012

Thermodynamics of Ionization of Aqueous Methoxy Phenols

Frank J. Mulero, J. C. Ahluwalia, Loren G. Helper

Ocean Sciences

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6 Scopus citations

Abstract

Heats of ionization of o-methoxy phenol, m-methoxy phenol and p-methoxy phenol in aqueous solution have been determined calorimetrically. Combination of our results with ΔF° values from ionization constants gives °S° values for ionization of these substituted phenols in aqueous solution. Interpretation of the thermodynamic data in terms of resonance and inductive effects and solute-solvent interactions is discussed briefly.

Original language	English (US)
Pages (from-to)	192-193
Number of pages	2
Journal	Journal of Chemical and Engineering Data
Volume	9
Issue number	2
DOIs	https://doi.org/10.1021/je60021a012
State	Published - Apr 1 1964

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ASJC Scopus subject areas

Chemistry(all)
Chemical Engineering(all)

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Mulero, F. J., Ahluwalia, J. C., & Helper, L. G. (1964). Thermodynamics of Ionization of Aqueous Methoxy Phenols. Journal of Chemical and Engineering Data, 9(2), 192-193. https://doi.org/10.1021/je60021a012

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abstract = "Heats of ionization of o-methoxy phenol, m-methoxy phenol and p-methoxy phenol in aqueous solution have been determined calorimetrically. Combination of our results with ΔF° values from ionization constants gives °S° values for ionization of these substituted phenols in aqueous solution. Interpretation of the thermodynamic data in terms of resonance and inductive effects and solute-solvent interactions is discussed briefly.",

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N2 - Heats of ionization of o-methoxy phenol, m-methoxy phenol and p-methoxy phenol in aqueous solution have been determined calorimetrically. Combination of our results with ΔF° values from ionization constants gives °S° values for ionization of these substituted phenols in aqueous solution. Interpretation of the thermodynamic data in terms of resonance and inductive effects and solute-solvent interactions is discussed briefly.

AB - Heats of ionization of o-methoxy phenol, m-methoxy phenol and p-methoxy phenol in aqueous solution have been determined calorimetrically. Combination of our results with ΔF° values from ionization constants gives °S° values for ionization of these substituted phenols in aqueous solution. Interpretation of the thermodynamic data in terms of resonance and inductive effects and solute-solvent interactions is discussed briefly.

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10.1021/je60021a012