Thermodynamics of ionization of aqueous methoxy phenols

Frank J Millero, J. C. Ahluwalia, G. Hepler

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

Heats of ionization of o-methoxy phenol, m-methoxy phenol and p-methoxy phenol in aqueous solution have been determined calorimetrically. Combination of our results with ΔF° values from ionization constants gives ΔS° values for ionization of these substituted phenols in aqueous solution. Interpretation of the thermodynamic data in terms of resonance and inductive effects and solute-solvent interactions it discussed briefly.

Original languageEnglish (US)
Pages (from-to)192-193
Number of pages2
JournalJournal of Chemical and Engineering Data
Volume9
Issue number2
StatePublished - 1964
Externally publishedYes

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Phenols
Phenol
Ionization
Thermodynamics

ASJC Scopus subject areas

  • Chemical Engineering(all)
  • Chemistry(all)

Cite this

Millero, F. J., Ahluwalia, J. C., & Hepler, G. (1964). Thermodynamics of ionization of aqueous methoxy phenols. Journal of Chemical and Engineering Data, 9(2), 192-193.

Thermodynamics of ionization of aqueous methoxy phenols. / Millero, Frank J; Ahluwalia, J. C.; Hepler, G.

In: Journal of Chemical and Engineering Data, Vol. 9, No. 2, 1964, p. 192-193.

Research output: Contribution to journalArticle

Millero, FJ, Ahluwalia, JC & Hepler, G 1964, 'Thermodynamics of ionization of aqueous methoxy phenols', Journal of Chemical and Engineering Data, vol. 9, no. 2, pp. 192-193.
Millero, Frank J ; Ahluwalia, J. C. ; Hepler, G. / Thermodynamics of ionization of aqueous methoxy phenols. In: Journal of Chemical and Engineering Data. 1964 ; Vol. 9, No. 2. pp. 192-193.
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