Abstract
Heats of ionization of o-methoxy phenol, m-methoxy phenol and p-methoxy phenol in aqueous solution have been determined calorimetrically. Combination of our results with ΔF° values from ionization constants gives ΔS° values for ionization of these substituted phenols in aqueous solution. Interpretation of the thermodynamic data in terms of resonance and inductive effects and solute-solvent interactions it discussed briefly.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 192-193 |
| Number of pages | 2 |
| Journal | Journal of Chemical and Engineering Data |
| Volume | 9 |
| Issue number | 2 |
| State | Published - 1964 |
| Externally published | Yes |
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ASJC Scopus subject areas
- Chemical Engineering(all)
- Chemistry(all)
Cite this
Thermodynamics of ionization of aqueous methoxy phenols. / Millero, Frank J; Ahluwalia, J. C.; Hepler, G.
In: Journal of Chemical and Engineering Data, Vol. 9, No. 2, 1964, p. 192-193.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Thermodynamics of ionization of aqueous methoxy phenols
AU - Millero, Frank J
AU - Ahluwalia, J. C.
AU - Hepler, G.
PY - 1964
Y1 - 1964
N2 - Heats of ionization of o-methoxy phenol, m-methoxy phenol and p-methoxy phenol in aqueous solution have been determined calorimetrically. Combination of our results with ΔF° values from ionization constants gives ΔS° values for ionization of these substituted phenols in aqueous solution. Interpretation of the thermodynamic data in terms of resonance and inductive effects and solute-solvent interactions it discussed briefly.
AB - Heats of ionization of o-methoxy phenol, m-methoxy phenol and p-methoxy phenol in aqueous solution have been determined calorimetrically. Combination of our results with ΔF° values from ionization constants gives ΔS° values for ionization of these substituted phenols in aqueous solution. Interpretation of the thermodynamic data in terms of resonance and inductive effects and solute-solvent interactions it discussed briefly.
UR - http://www.scopus.com/inward/record.url?scp=33947482113&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=33947482113&partnerID=8YFLogxK
M3 - Article
VL - 9
SP - 192
EP - 193
JO - Journal of Chemical & Engineering Data
JF - Journal of Chemical & Engineering Data
SN - 0021-9568
IS - 2
ER -