Theoretical studies of the spin dynamics of quadrupolar nuclei at rotational resonance conditions

Jamie D. Walls, Kwang Hun Lim, Alexander Pines

Research output: Contribution to journalArticlepeer-review

17 Scopus citations

Abstract

A theory of the excitation and conversion between multiple-quantum coherences in spin I=3/2 quadrupolar nuclei in powdered samples in the sudden-passage limit is presented. The theory is applicable to rf irradiation even at RR conditions (ω1=nωr and may be extended to include resonance offset and second-order quadropolar effects, as well as potentially generalized to the treatment of Igt;3/2 nuclei.

Original languageEnglish (US)
Pages (from-to)79-90
Number of pages12
JournalJournal of Chemical Physics
Volume116
Issue number1
DOIs
StatePublished - Jan 1 2002
Externally publishedYes

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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