Theoretical investigations of l = 5/2 quadrupolar spin dynamics in the sudden-passage regime

Jamie D. Walls, Kwang Hun Lim, John W. Logan, Jeffry T. Urban, Alexej Jerschow, Alexander Pines

Research output: Contribution to journalArticle

4 Scopus citations

Abstract

The theoretical investigations of quadrupolar spin dynmaics was studied using bimodal Floquet theory. Effective transfer between five-quantum and triple-quantum coherences was observed in between rotary resonance conditions. The results revealed that rotary resonance effects occur when the strength of the radio-frequency irradiation matches the sample spinning speed.

Original languageEnglish (US)
Pages (from-to)518-532
Number of pages15
JournalJournal of Chemical Physics
Volume117
Issue number2
DOIs
StatePublished - Jul 8 2002

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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