The speciation of ions in Tiber river estuary waters

Frank J. Millero; Giuseppe Macchi; Maurizio Pettine

doi:10.1016/S0302-3524(81)80055-2

The speciation of ions in Tiber river estuary waters

Frank J. Millero, Giuseppe Macchi, Maurizio Pettine

Ocean Sciences

Research output: Contribution to journal › Article

7 Scopus citations

Abstract

The composition of the major ionic constituents of the Tiber river waters has been analyzed from literature data. The ratio of the major cations and anions to chloride are strongly influenced by tributary waters (Paglia, Nera and Aniene rivers). The speciation of the major cations and anions have been determined for waters formed by mixing lower Tiber river waters and Tyrrhenian sea waters of constant composition. The results are compared to similar calculations for mixing average river waters with seawater. The total or stoichiometric activity coefficients for the major ionic components have been determined from the speciation results. Values for the ionization constant of weak acids in the waters were found to be in reasonable agreement with values determined at the same absolute salinity.

Original language	English (US)
Pages (from-to)	517-534
Number of pages	18
Journal	Estuarine, Coastal and Shelf Science
Volume	13
Issue number	5
DOIs	https://doi.org/10.1016/S0302-3524(81)80055-2
State	Published - Nov 1981

Keywords

Tyrrhenian sea
estuaries
ions
speciation

ASJC Scopus subject areas

Oceanography
Aquatic Science

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10.1016/S0302-3524(81)80055-2

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Millero, F. J., Macchi, G., & Pettine, M. (1981). The speciation of ions in Tiber river estuary waters. Estuarine, Coastal and Shelf Science, 13(5), 517-534. https://doi.org/10.1016/S0302-3524(81)80055-2

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AB - The composition of the major ionic constituents of the Tiber river waters has been analyzed from literature data. The ratio of the major cations and anions to chloride are strongly influenced by tributary waters (Paglia, Nera and Aniene rivers). The speciation of the major cations and anions have been determined for waters formed by mixing lower Tiber river waters and Tyrrhenian sea waters of constant composition. The results are compared to similar calculations for mixing average river waters with seawater. The total or stoichiometric activity coefficients for the major ionic components have been determined from the speciation results. Values for the ionization constant of weak acids in the waters were found to be in reasonable agreement with values determined at the same absolute salinity.

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