The self-assembly of a highly ordered [2]catenane

Peter R. Ashton, Christopher L. Brown, Ewan J.T. Chrystal, Timothy T. Goodnow, Angel E. Kaifer, Keith P. Parry, Douglas Philp, Alexandra M.Z. Slawin, Neil Spencer, J. Fraser Stoddart, David J. Williams

Research output: Contribution to journalArticle

75 Scopus citations

Abstract

Template-directed synthesis has been used to construct a [2]catenane in which the two molecular components, the cyclobis(paraquat-p-phenylene) tetracation and 1,5-dinaphtho-38-crown-10, are found to be ordered non-covalently with respect to each other in both the solid (by X-ray crystallography) and solution (by NMR spectroscopy) states and to influence each other to the extent of establishing electrochemical gradients for the stepwise one electron reductions of the two paraquat units.

Original languageEnglish (US)
Pages (from-to)634-639
Number of pages6
JournalJournal of the Chemical Society, Chemical Communications
Issue number9
DOIs
StatePublished - 1991

ASJC Scopus subject areas

  • Molecular Medicine

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    Ashton, P. R., Brown, C. L., Chrystal, E. J. T., Goodnow, T. T., Kaifer, A. E., Parry, K. P., Philp, D., Slawin, A. M. Z., Spencer, N., Stoddart, J. F., & Williams, D. J. (1991). The self-assembly of a highly ordered [2]catenane. Journal of the Chemical Society, Chemical Communications, (9), 634-639. https://doi.org/10.1039/C39910000634