Abstract
Isoprene, 1,3-butadiene and 2,3-dimethyl-1,3-butadiene react with HFe(CO)4SiCl3 by addition of the FeH function to the diene. Isoprene appears to add predominantly 1,4 and 2,3-dimethyl-1,3-butadiene appears to add 1,2, while 1,3-butadiene may add both ways. In the case of isoprene and 1,3-butadiene loss of CO from the addition compound gives a stable π-allyl- Fe(Co)3SiCl3 product. Either cis- or trans-1,3-pentadiene is reduced to pentene by HFe(CO)4SiCl3.
Original language | English (US) |
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Pages (from-to) | 467-475 |
Number of pages | 9 |
Journal | Journal of Organometallic Chemistry |
Volume | 160 |
Issue number | 2 |
DOIs | |
State | Published - Nov 7 1978 |
Externally published | Yes |
ASJC Scopus subject areas
- Biochemistry
- Physical and Theoretical Chemistry
- Organic Chemistry
- Inorganic Chemistry
- Materials Chemistry