The reaction of trichlorosilyltetracarbonyliron hydride (HFe(CO)4SiCl3) with conjugated dienes

John W. Connolly; Carl D. Hoff

doi:10.1016/S0022-328X(00)89103-2

The reaction of trichlorosilyltetracarbonyliron hydride (HFe(CO)₄SiCl₃) with conjugated dienes

John W. Connolly, Carl D. Hoff

Research output: Contribution to journal › Article › peer-review

15 Scopus citations

Abstract

Isoprene, 1,3-butadiene and 2,3-dimethyl-1,3-butadiene react with HFe(CO)₄SiCl₃ by addition of the FeH function to the diene. Isoprene appears to add predominantly 1,4 and 2,3-dimethyl-1,3-butadiene appears to add 1,2, while 1,3-butadiene may add both ways. In the case of isoprene and 1,3-butadiene loss of CO from the addition compound gives a stable π-allyl- Fe(Co)₃SiCl₃ product. Either cis- or trans-1,3-pentadiene is reduced to pentene by HFe(CO)₄SiCl₃.

Original language	English (US)
Pages (from-to)	467-475
Number of pages	9
Journal	Journal of Organometallic Chemistry
Volume	160
Issue number	2
DOIs	https://doi.org/10.1016/S0022-328X(00)89103-2
State	Published - Nov 7 1978
Externally published	Yes

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

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title = "The reaction of trichlorosilyltetracarbonyliron hydride (HFe(CO)4SiCl3) with conjugated dienes",

abstract = "Isoprene, 1,3-butadiene and 2,3-dimethyl-1,3-butadiene react with HFe(CO)4SiCl3 by addition of the FeH function to the diene. Isoprene appears to add predominantly 1,4 and 2,3-dimethyl-1,3-butadiene appears to add 1,2, while 1,3-butadiene may add both ways. In the case of isoprene and 1,3-butadiene loss of CO from the addition compound gives a stable π-allyl- Fe(Co)3SiCl3 product. Either cis- or trans-1,3-pentadiene is reduced to pentene by HFe(CO)4SiCl3.",

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AU - Hoff, Carl D.

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N2 - Isoprene, 1,3-butadiene and 2,3-dimethyl-1,3-butadiene react with HFe(CO)4SiCl3 by addition of the FeH function to the diene. Isoprene appears to add predominantly 1,4 and 2,3-dimethyl-1,3-butadiene appears to add 1,2, while 1,3-butadiene may add both ways. In the case of isoprene and 1,3-butadiene loss of CO from the addition compound gives a stable π-allyl- Fe(Co)3SiCl3 product. Either cis- or trans-1,3-pentadiene is reduced to pentene by HFe(CO)4SiCl3.

AB - Isoprene, 1,3-butadiene and 2,3-dimethyl-1,3-butadiene react with HFe(CO)4SiCl3 by addition of the FeH function to the diene. Isoprene appears to add predominantly 1,4 and 2,3-dimethyl-1,3-butadiene appears to add 1,2, while 1,3-butadiene may add both ways. In the case of isoprene and 1,3-butadiene loss of CO from the addition compound gives a stable π-allyl- Fe(Co)3SiCl3 product. Either cis- or trans-1,3-pentadiene is reduced to pentene by HFe(CO)4SiCl3.

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