The influence of chiral auxiliaries is enhanced within zeolites

S. Jayaraman, S. Uppili, A. Natarajan, A. Joy, K. C W Chong, M. R. Netherton, A. Zenova, J. R. Scheffer, Vaidhyanathan Ramamurthy

Research output: Contribution to journalArticle

23 Citations (Scopus)

Abstract

Zeolites significantly enhance the influence of chiral auxiliaries during photochemical reactions. The generality of this phenomenon has been tested with three independent examples. Chiral auxiliaries that lead to 1:1 mixtures of diastereomers in solution give products in up to 80% diastereomeric excess in the presence of faujasite type zeolites. (C) 2000 Elsevier Science Ltd.

Original languageEnglish
Pages (from-to)8231-8235
Number of pages5
JournalTetrahedron Letters
Volume41
Issue number43
StatePublished - Oct 21 2000
Externally publishedYes

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Zeolites
Photochemical reactions
faujasite

ASJC Scopus subject areas

  • Biochemistry
  • Organic Chemistry
  • Drug Discovery

Cite this

Jayaraman, S., Uppili, S., Natarajan, A., Joy, A., Chong, K. C. W., Netherton, M. R., ... Ramamurthy, V. (2000). The influence of chiral auxiliaries is enhanced within zeolites. Tetrahedron Letters, 41(43), 8231-8235.

The influence of chiral auxiliaries is enhanced within zeolites. / Jayaraman, S.; Uppili, S.; Natarajan, A.; Joy, A.; Chong, K. C W; Netherton, M. R.; Zenova, A.; Scheffer, J. R.; Ramamurthy, Vaidhyanathan.

In: Tetrahedron Letters, Vol. 41, No. 43, 21.10.2000, p. 8231-8235.

Research output: Contribution to journalArticle

Jayaraman, S, Uppili, S, Natarajan, A, Joy, A, Chong, KCW, Netherton, MR, Zenova, A, Scheffer, JR & Ramamurthy, V 2000, 'The influence of chiral auxiliaries is enhanced within zeolites', Tetrahedron Letters, vol. 41, no. 43, pp. 8231-8235.
Jayaraman S, Uppili S, Natarajan A, Joy A, Chong KCW, Netherton MR et al. The influence of chiral auxiliaries is enhanced within zeolites. Tetrahedron Letters. 2000 Oct 21;41(43):8231-8235.
Jayaraman, S. ; Uppili, S. ; Natarajan, A. ; Joy, A. ; Chong, K. C W ; Netherton, M. R. ; Zenova, A. ; Scheffer, J. R. ; Ramamurthy, Vaidhyanathan. / The influence of chiral auxiliaries is enhanced within zeolites. In: Tetrahedron Letters. 2000 ; Vol. 41, No. 43. pp. 8231-8235.
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