TY - JOUR
T1 - The fluorescence spectrum and lifetime of the anthracene/trans, trans-2,4-Hexadiene exciplex
AU - Watson, Brant D.
AU - Townsend, David E.
AU - Saltiel, Jack
N1 - Funding Information:
This work wass upportedb y National ScienceF oun-dation Grants No. MPS7421093 and MPS 76-02439, and by a contract betweent he Division of Biomedical and EnvironmentalR esearch,U .S. Atomic Energy Com-missiona nd Florida State University.
Copyright:
Copyright 2014 Elsevier B.V., All rights reserved.
PY - 1976/10/15
Y1 - 1976/10/15
N2 - A weak transient fluorescence (φf ≈ 0.0036 and τ ≈ 27 ns) has been detected by employing single photon counting methods from solutions of anthracene, 6.7 × 10-5 M, and trans, trans-2,4-hexadiene, 1.76 M. This emission is tentatively assigned to the anthracene/1,3-diene exciplex and appears to confirm the mechanism for 1,3-diene enhanced anthracene photodimerization previously proposed for this system.
AB - A weak transient fluorescence (φf ≈ 0.0036 and τ ≈ 27 ns) has been detected by employing single photon counting methods from solutions of anthracene, 6.7 × 10-5 M, and trans, trans-2,4-hexadiene, 1.76 M. This emission is tentatively assigned to the anthracene/1,3-diene exciplex and appears to confirm the mechanism for 1,3-diene enhanced anthracene photodimerization previously proposed for this system.
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U2 - 10.1016/0009-2614(76)85306-7
DO - 10.1016/0009-2614(76)85306-7
M3 - Article
AN - SCOPUS:49549134192
VL - 43
SP - 295
EP - 298
JO - Chemical Physics Letters
JF - Chemical Physics Letters
SN - 0009-2614
IS - 2
ER -