Tetrathiafulvalene-functionalized cavitands as building blocks for redox active hemicarcerands

Sandra Mendoza, Luis A. Godínez, Angel E. Kaifer

Research output: Contribution to journalArticle

14 Scopus citations

Abstract

Two new cavitands bearing four upper-rim tetrathiafulvalene (TTF) units were synthesized. One of these cavitands was used to prepare a redox-active hemicarcerand containing four TTF subunits covalently appended to its equatorial region. Preliminary electrochemical characterization data show that the four TTF residues in all these compounds behave as independent, non-interacting groups in their heterogeneous electron transfer reactions.

Original languageEnglish (US)
Pages (from-to)165-169
Number of pages5
JournalSupramolecular Chemistry
Volume16
Issue number3
DOIs
StatePublished - Apr 1 2004

Keywords

  • Cavitand
  • Electrochemistry
  • Hemicarcerand
  • Tetrathiafulvalene

ASJC Scopus subject areas

  • Chemistry(all)

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