Synthesis and reactions of the transition metal substituted tin hydride HSn[Mo(CO)3C5H5]3

Carl D. Hoff, John W. Connolly

Research output: Contribution to journalArticle

9 Scopus citations

Abstract

Reaction of HMo(CO)3C5H5 and Sn(C5H5)2 produces the tin hydride HSn[Mo(CO)3C5H5]3 (I). Reaction of I with CCl4, CHCl3, or CH2Cl2 gives ClSn[Mo(CO)3C5H5]3 (II). With hydrogen chloride the hydride I reacts to produce the dichloride Cl2Sn[Mo(CO)3C5H5]2. The first step in this reaction is cleavage of the SnH bond to produce the chloride II. The hydride I reacts with acetic acid to produce the diacetate (CH3COO)2Sn[Mo(CO)3C5H5]2.

Original languageEnglish (US)
Pages (from-to)127-135
Number of pages9
JournalJournal of Organometallic Chemistry
Volume148
Issue number2
DOIs
StatePublished - Mar 21 1978
Externally publishedYes

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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