Synthesis and reactions of the transition metal substituted tin hydride HSn[Mo(CO)3C5H5]3

Carl Hoff, John W. Connolly

Research output: Contribution to journalArticle

9 Citations (Scopus)

Abstract

Reaction of HMo(CO)3C5H5 and Sn(C5H5)2 produces the tin hydride HSn[Mo(CO)3C5H5]3 (I). Reaction of I with CCl4, CHCl3, or CH2Cl2 gives ClSn[Mo(CO)3C5H5]3 (II). With hydrogen chloride the hydride I reacts to produce the dichloride Cl2Sn[Mo(CO)3C5H5]2. The first step in this reaction is cleavage of the SnH bond to produce the chloride II. The hydride I reacts with acetic acid to produce the diacetate (CH3COO)2Sn[Mo(CO)3C5H5]2.

Original languageEnglish
Pages (from-to)127-135
Number of pages9
JournalJournal of Organometallic Chemistry
Volume148
Issue number2
DOIs
StatePublished - Mar 21 1978
Externally publishedYes

Fingerprint

Tin
Carbon Monoxide
Hydrides
hydrides
Transition metals
tin
Metals
transition metals
synthesis
hydrogen chlorides
dichlorides
acetic acid
Acetic acid
cleavage
chlorides
Hydrochloric Acid
Hydrogen
Acetic Acid
Chlorides

ASJC Scopus subject areas

  • Biochemistry
  • Chemical Engineering (miscellaneous)
  • Inorganic Chemistry
  • Organic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Science (miscellaneous)
  • Materials Chemistry

Cite this

Synthesis and reactions of the transition metal substituted tin hydride HSn[Mo(CO)3C5H5]3. / Hoff, Carl; Connolly, John W.

In: Journal of Organometallic Chemistry, Vol. 148, No. 2, 21.03.1978, p. 127-135.

Research output: Contribution to journalArticle

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AB - Reaction of HMo(CO)3C5H5 and Sn(C5H5)2 produces the tin hydride HSn[Mo(CO)3C5H5]3 (I). Reaction of I with CCl4, CHCl3, or CH2Cl2 gives ClSn[Mo(CO)3C5H5]3 (II). With hydrogen chloride the hydride I reacts to produce the dichloride Cl2Sn[Mo(CO)3C5H5]2. The first step in this reaction is cleavage of the SnH bond to produce the chloride II. The hydride I reacts with acetic acid to produce the diacetate (CH3COO)2Sn[Mo(CO)3C5H5]2.

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