Abstract
The new tetrahedral complex Os4(CO)12[Pd(PBu 3t)]4, 3, was obtained from the reaction of Os3(CO)12 with Pd(PBu3t)2 in octane solution at reflux. Compound 3 was characterized by IR, 1H and 31P NMR spectroscopy, mass spectroscopy, and single-crystal X-ray diffraction analysis. The electronic structure of 3 was evaluated by Fenske-Hall molecular orbital analysis. Compound 3 is electronically unsaturated and reacts with hydrogen at room temperature to yield the known compound Os4(CO)12(μ-H)4, 4.
| Original language | English |
|---|---|
| Pages (from-to) | 1169-1173 |
| Number of pages | 5 |
| Journal | Organometallics |
| Volume | 27 |
| Issue number | 6 |
| DOIs | |
| State | Published - Mar 24 2008 |
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ASJC Scopus subject areas
- Inorganic Chemistry
- Organic Chemistry
Cite this
Synthesis and properties of an unusual new high-symmetry osmium-palladium carbonyl cluster complex. / Adams, Richard D.; Boswell, Erin M.; Captain, Burjor.
In: Organometallics, Vol. 27, No. 6, 24.03.2008, p. 1169-1173.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Synthesis and properties of an unusual new high-symmetry osmium-palladium carbonyl cluster complex
AU - Adams, Richard D.
AU - Boswell, Erin M.
AU - Captain, Burjor
PY - 2008/3/24
Y1 - 2008/3/24
N2 - The new tetrahedral complex Os4(CO)12[Pd(PBu 3t)]4, 3, was obtained from the reaction of Os3(CO)12 with Pd(PBu3t)2 in octane solution at reflux. Compound 3 was characterized by IR, 1H and 31P NMR spectroscopy, mass spectroscopy, and single-crystal X-ray diffraction analysis. The electronic structure of 3 was evaluated by Fenske-Hall molecular orbital analysis. Compound 3 is electronically unsaturated and reacts with hydrogen at room temperature to yield the known compound Os4(CO)12(μ-H)4, 4.
AB - The new tetrahedral complex Os4(CO)12[Pd(PBu 3t)]4, 3, was obtained from the reaction of Os3(CO)12 with Pd(PBu3t)2 in octane solution at reflux. Compound 3 was characterized by IR, 1H and 31P NMR spectroscopy, mass spectroscopy, and single-crystal X-ray diffraction analysis. The electronic structure of 3 was evaluated by Fenske-Hall molecular orbital analysis. Compound 3 is electronically unsaturated and reacts with hydrogen at room temperature to yield the known compound Os4(CO)12(μ-H)4, 4.
UR - http://www.scopus.com/inward/record.url?scp=41749120555&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=41749120555&partnerID=8YFLogxK
U2 - 10.1021/om701206r
DO - 10.1021/om701206r
M3 - Article
AN - SCOPUS:41749120555
VL - 27
SP - 1169
EP - 1173
JO - Organometallics
JF - Organometallics
SN - 0276-7333
IS - 6
ER -