Abstract
The new tetrahedral complex Os4(CO)12[Pd(PBu 3t)]4, 3, was obtained from the reaction of Os3(CO)12 with Pd(PBu3t)2 in octane solution at reflux. Compound 3 was characterized by IR, 1H and 31P NMR spectroscopy, mass spectroscopy, and single-crystal X-ray diffraction analysis. The electronic structure of 3 was evaluated by Fenske-Hall molecular orbital analysis. Compound 3 is electronically unsaturated and reacts with hydrogen at room temperature to yield the known compound Os4(CO)12(μ-H)4, 4.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 1169-1173 |
| Number of pages | 5 |
| Journal | Organometallics |
| Volume | 27 |
| Issue number | 6 |
| DOIs | |
| State | Published - Mar 24 2008 |
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Organic Chemistry
- Inorganic Chemistry
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Adams, R. D., Boswell, E. M., & Captain, B. (2008). Synthesis and properties of an unusual new high-symmetry osmium-palladium carbonyl cluster complex. Organometallics, 27(6), 1169-1173. https://doi.org/10.1021/om701206r