Synthesis and application of a permanently immobilized olefin-metathesis catalyst

Stephan C Schuerer; Simon Gessler; Nicole Buschmann; Siegfried Blechert

doi:10.1002/1521-3773(20001103)39:21<3801::AID-ANIE3801>3.0.CO;2-J

Synthesis and application of a permanently immobilized olefin-metathesis catalyst

Stephan C Schuerer, Simon Gessler, Nicole Buschmann, Siegfried Blechert

Research output: Contribution to journal › Article › peer-review

Abstract

Immobilized on Merrifield polystyrene, catalyst 1 shows high activity and stability in different types of olefin metathesis. The products can be isolated in high purity by simple filtration, while the immobilized catalyst 1 can be recycled and used up to four times in the ring-closing metathesis of 2. Mes = methane sulfonate, Ts = toluene sulfonate, Cy = cyclohexyl.

Original language	English (US)
Pages (from-to)	3898-3901
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	39
Issue number	21
DOIs	https://doi.org/10.1002/1521-3773(20001103)39:21<3801::AID-ANIE3801>3.0.CO;2-J
State	Published - Nov 3 2000
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Chemistry(all)

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AU - Blechert, Siegfried

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AB - Immobilized on Merrifield polystyrene, catalyst 1 shows high activity and stability in different types of olefin metathesis. The products can be isolated in high purity by simple filtration, while the immobilized catalyst 1 can be recycled and used up to four times in the ring-closing metathesis of 2. Mes = methane sulfonate, Ts = toluene sulfonate, Cy = cyclohexyl.

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