Abstract
The use of supramolecular architectures to control the spatially dependent spin exchange (spin communication) between two covalently linked radical centers (biradical) has been explored. Cucurbit[8]uril, through supramolecular steric effect, completely suppresses spin exchange between two adjacent radical centers in a biradical.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 7736-7738 |
| Number of pages | 3 |
| Journal | Chemical Communications |
| Volume | 46 |
| Issue number | 41 |
| DOIs | |
| State | Published - Nov 7 2010 |
ASJC Scopus subject areas
- Catalysis
- Electronic, Optical and Magnetic Materials
- Ceramics and Composites
- Chemistry(all)
- Surfaces, Coatings and Films
- Metals and Alloys
- Materials Chemistry
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Cite this
Porel, M., Ottaviani, M. F., Jockusch, S., Jayaraj, N., Turro, N. J., & Ramamurthy, V. (2010). Suppression of spin-spin coupling in nitroxyl biradicals by supramolecular host-guest interactions. Chemical Communications, 46(41), 7736-7738. https://doi.org/10.1039/c0cc02587a