Superloading of tin ligands into rhodium and iridium carbonyl cluster complexes

Richard D. Adams, Burjor Captain, Jack L. Smith, Michael B. Hall, Chad L. Beddie, Charles Edwin Webster

Research output: Contribution to journalArticlepeer-review

62 Scopus citations

Abstract

The reactions of Rh4(CO)12 and Ir4(CO) 12 with Ph3SnH have yielded the new Rh-Sn and Ir-Sn cluster complexes M3(CO)6(μ-SnPh2) 3-(SnPh3)3,1 (M = Rh) and 2 (M = Ir). Both compounds contain triangular M3 clusters with three bridging SnPh2 and three terminal SnPh3 ligands. The M-M bonds are unusually long. Molecular orbital calculations indicate that this is due to the importance of M-Sn bonding and weak direct M-M interactions. Reaction of 1 with Ph3SnH at reflux in 1,2-dichlorobenzene solvent yielded the complex Rh3(CO)3(SnPh3)3(μ-SnPh 2)33-SnPh)2, 3, which contains eight tin ligands: three terminal SnPh3, three edge-bridging SnPh2, and two triply bridging SnPh ligands.

Original languageEnglish (US)
Pages (from-to)7576-7578
Number of pages3
JournalInorganic Chemistry
Volume43
Issue number24
DOIs
StatePublished - Nov 29 2004
Externally publishedYes

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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