Structural and solution calorimetric studies of sulfur binding to nucleophilic carbenes

Jinkun Huang, Hans Jörg Schanz, E. D. Stevens, Steven P. Nolan, Kenneth B. Capps, Andreas Bauer, Carl Hoff

Research output: Contribution to journalArticle

38 Citations (Scopus)

Abstract

The enthalpy of sulfur atom transfer to stable cyclic carbenes has been measured by solution calorimetry. Absolute values of the R2C=S bond strengths (≃100 kcal/mol) are in a range comparable to those of R3P=S bond strengths. These data are compared to reported enthalpies of binding of carbenes and phosphines to metal complexes. Similar patterns of donor abilities are displayed for both oxidative addition of sulfur and binding to metal complexes.

Original languageEnglish
Pages (from-to)1042-1045
Number of pages4
JournalInorganic Chemistry
Volume39
Issue number5
DOIs
StatePublished - Mar 6 2000

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Coordination Complexes
carbenes
Sulfur
Enthalpy
sulfur
enthalpy
Phosphines
Calorimetry
phosphines
metals
heat measurement
Atoms
atoms
carbene

ASJC Scopus subject areas

  • Inorganic Chemistry

Cite this

Huang, J., Schanz, H. J., Stevens, E. D., Nolan, S. P., Capps, K. B., Bauer, A., & Hoff, C. (2000). Structural and solution calorimetric studies of sulfur binding to nucleophilic carbenes. Inorganic Chemistry, 39(5), 1042-1045. https://doi.org/10.1021/ic990906+

Structural and solution calorimetric studies of sulfur binding to nucleophilic carbenes. / Huang, Jinkun; Schanz, Hans Jörg; Stevens, E. D.; Nolan, Steven P.; Capps, Kenneth B.; Bauer, Andreas; Hoff, Carl.

In: Inorganic Chemistry, Vol. 39, No. 5, 06.03.2000, p. 1042-1045.

Research output: Contribution to journalArticle

Huang, J, Schanz, HJ, Stevens, ED, Nolan, SP, Capps, KB, Bauer, A & Hoff, C 2000, 'Structural and solution calorimetric studies of sulfur binding to nucleophilic carbenes', Inorganic Chemistry, vol. 39, no. 5, pp. 1042-1045. https://doi.org/10.1021/ic990906+
Huang J, Schanz HJ, Stevens ED, Nolan SP, Capps KB, Bauer A et al. Structural and solution calorimetric studies of sulfur binding to nucleophilic carbenes. Inorganic Chemistry. 2000 Mar 6;39(5):1042-1045. https://doi.org/10.1021/ic990906+
Huang, Jinkun ; Schanz, Hans Jörg ; Stevens, E. D. ; Nolan, Steven P. ; Capps, Kenneth B. ; Bauer, Andreas ; Hoff, Carl. / Structural and solution calorimetric studies of sulfur binding to nucleophilic carbenes. In: Inorganic Chemistry. 2000 ; Vol. 39, No. 5. pp. 1042-1045.
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