Strategies to switch fluorescence with photochromic oxazines

Erhan Deniz, Janet Cusido, Massimiliano Tomasulo, Mutlu Battal, Ibrahim Yildiz, Marco Petriella, Mariano L. Bossi, Salvatore Sortino, Francisco Raymo

Research output: Chapter in Book/Report/Conference proceedingChapter

Abstract

Photochromic compounds switch reversibly between states with distinct absorption properties in the visible region under the influence of optical stimulation. This chapter deals with switching of fluorescence with photochromic oxazines. It describes the design and synthesis of fluorophore-oxazine dyads, and discusses fluorescence activation with fluorophore-oxazine dyads. The unique combination of photochemical and photophysical properties associated with the fluorophore-photochrome dyads entrapped within the micelles offers the opportunity to overcome diffraction and resolve structural features at the nanoscale. Our strategies for fluorescence activation with photochromic oxazines can eventually lead to the realization of an entire family of photoswitchable fluorophores for the visualization of biological samples with subdiffraction resolution.

Original languageEnglish (US)
Title of host publicationOrganic Synthesis and Molecular Engineering
Publisherwiley
Pages197-212
Number of pages16
ISBN (Electronic)9781118736449
ISBN (Print)9781118150924
DOIs
StatePublished - Oct 25 2013

Fingerprint

Oxazines
Fluorophores
Fluorescence
Switches
Chemical activation
Micelles
Visualization
Diffraction

Keywords

  • Fluorescence activation
  • Fluorophore-oxazine dyads
  • Photochromic oxazines
  • Subdiffraction resolution

ASJC Scopus subject areas

  • Chemistry(all)
  • Engineering(all)

Cite this

Deniz, E., Cusido, J., Tomasulo, M., Battal, M., Yildiz, I., Petriella, M., ... Raymo, F. (2013). Strategies to switch fluorescence with photochromic oxazines. In Organic Synthesis and Molecular Engineering (pp. 197-212). wiley. https://doi.org/10.1002/9781118736449.ch7

Strategies to switch fluorescence with photochromic oxazines. / Deniz, Erhan; Cusido, Janet; Tomasulo, Massimiliano; Battal, Mutlu; Yildiz, Ibrahim; Petriella, Marco; Bossi, Mariano L.; Sortino, Salvatore; Raymo, Francisco.

Organic Synthesis and Molecular Engineering. wiley, 2013. p. 197-212.

Research output: Chapter in Book/Report/Conference proceedingChapter

Deniz, E, Cusido, J, Tomasulo, M, Battal, M, Yildiz, I, Petriella, M, Bossi, ML, Sortino, S & Raymo, F 2013, Strategies to switch fluorescence with photochromic oxazines. in Organic Synthesis and Molecular Engineering. wiley, pp. 197-212. https://doi.org/10.1002/9781118736449.ch7
Deniz E, Cusido J, Tomasulo M, Battal M, Yildiz I, Petriella M et al. Strategies to switch fluorescence with photochromic oxazines. In Organic Synthesis and Molecular Engineering. wiley. 2013. p. 197-212 https://doi.org/10.1002/9781118736449.ch7
Deniz, Erhan ; Cusido, Janet ; Tomasulo, Massimiliano ; Battal, Mutlu ; Yildiz, Ibrahim ; Petriella, Marco ; Bossi, Mariano L. ; Sortino, Salvatore ; Raymo, Francisco. / Strategies to switch fluorescence with photochromic oxazines. Organic Synthesis and Molecular Engineering. wiley, 2013. pp. 197-212
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