Spectroscopic detection and theoretical confirmation of the role of Cr 2(CO)5(C5R5)2 and ·Cr(CO)2(ketene)(C5R5) as intermediates in carbonylation of N=N=CHSiMe3 to O=C=CHSiMe3 by ·Cr(CO)3(C5R5) (R = H, CH3)
George C. Fortman, Tamás Kégl, Qian Shu Li, Xiuhui Zhang, Henry F. Schaefer, Yaoming Xie, R. Bruce King, Joshua Telser, Carl D. Hoff
Dive into the research topics of 'Spectroscopic detection and theoretical confirmation of the role of Cr <sub>2</sub>(CO)<sub>5</sub>(C<sub>5</sub>R<sub>5</sub>)<sub>2</sub> and ·Cr(CO)<sub>2</sub>(ketene)(C<sub>5</sub>R<sub>5</sub>) as intermediates in carbonylation of N=N=CHSiMe<sub>3</sub> to O=C=CHSiMe<sub>3</sub> by ·Cr(CO)<sub>3</sub>(C<sub>5</sub>R<sub>5</sub>) (R = H, CH<sub>3</sub>)'. Together they form a unique fingerprint.