Specific volume of deuterium oxide from 2° to 40°C and 0 to 1000 bars applied pressure

Robert T. Emmet, Frank J Millero

Research output: Contribution to journalArticle

23 Citations (Scopus)

Abstract

Direct measurements of the specific volume of deuterium oxide (D2O) solutions were made with a magnetic float densimeter from 2° to 40°C and from 0 to 1000 bars applied pressure. The results were fitted to a second degree secant bulk modulus equation: (V0P)/(V0 - VP) = A0 + A1P + A2P2 + CP2- where V0 and VP are the specific volumes at zero and P applied pressure, A0 = 1/β0 the reciprocal of the 1 atm compressibilities, and A1 and A2 are temperature dependent parameters. The specific volumes were fitted to this equation with a standard deviation of 6 ppm over the entire pressure and temperature range. The equation of state of D2O was used to compute several thermodynamic properties that are compared to the results obtained by other workers from 5° to 40°C and 0 to 1000 bars.

Original languageEnglish (US)
Pages (from-to)351-356
Number of pages6
JournalJournal of Chemical and Engineering Data
Volume20
Issue number4
StatePublished - 1975

Fingerprint

Deuterium Oxide
Heavy water
Density (specific gravity)
Compressibility
Equations of state
Thermodynamic properties
Elastic moduli
Temperature

ASJC Scopus subject areas

  • Chemical Engineering(all)
  • Chemistry(all)

Cite this

Specific volume of deuterium oxide from 2° to 40°C and 0 to 1000 bars applied pressure. / Emmet, Robert T.; Millero, Frank J.

In: Journal of Chemical and Engineering Data, Vol. 20, No. 4, 1975, p. 351-356.

Research output: Contribution to journalArticle

@article{efe3e875920344218de671b729f632a9,
title = "Specific volume of deuterium oxide from 2° to 40°C and 0 to 1000 bars applied pressure",
abstract = "Direct measurements of the specific volume of deuterium oxide (D2O) solutions were made with a magnetic float densimeter from 2° to 40°C and from 0 to 1000 bars applied pressure. The results were fitted to a second degree secant bulk modulus equation: (V0P)/(V0 - VP) = A0 + A1P + A2P2 + CP2- where V0 and VP are the specific volumes at zero and P applied pressure, A0 = 1/β0 the reciprocal of the 1 atm compressibilities, and A1 and A2 are temperature dependent parameters. The specific volumes were fitted to this equation with a standard deviation of 6 ppm over the entire pressure and temperature range. The equation of state of D2O was used to compute several thermodynamic properties that are compared to the results obtained by other workers from 5° to 40°C and 0 to 1000 bars.",
author = "Emmet, {Robert T.} and Millero, {Frank J}",
year = "1975",
language = "English (US)",
volume = "20",
pages = "351--356",
journal = "Journal of Chemical & Engineering Data",
issn = "0021-9568",
publisher = "American Chemical Society",
number = "4",

}

TY - JOUR

T1 - Specific volume of deuterium oxide from 2° to 40°C and 0 to 1000 bars applied pressure

AU - Emmet, Robert T.

AU - Millero, Frank J

PY - 1975

Y1 - 1975

N2 - Direct measurements of the specific volume of deuterium oxide (D2O) solutions were made with a magnetic float densimeter from 2° to 40°C and from 0 to 1000 bars applied pressure. The results were fitted to a second degree secant bulk modulus equation: (V0P)/(V0 - VP) = A0 + A1P + A2P2 + CP2- where V0 and VP are the specific volumes at zero and P applied pressure, A0 = 1/β0 the reciprocal of the 1 atm compressibilities, and A1 and A2 are temperature dependent parameters. The specific volumes were fitted to this equation with a standard deviation of 6 ppm over the entire pressure and temperature range. The equation of state of D2O was used to compute several thermodynamic properties that are compared to the results obtained by other workers from 5° to 40°C and 0 to 1000 bars.

AB - Direct measurements of the specific volume of deuterium oxide (D2O) solutions were made with a magnetic float densimeter from 2° to 40°C and from 0 to 1000 bars applied pressure. The results were fitted to a second degree secant bulk modulus equation: (V0P)/(V0 - VP) = A0 + A1P + A2P2 + CP2- where V0 and VP are the specific volumes at zero and P applied pressure, A0 = 1/β0 the reciprocal of the 1 atm compressibilities, and A1 and A2 are temperature dependent parameters. The specific volumes were fitted to this equation with a standard deviation of 6 ppm over the entire pressure and temperature range. The equation of state of D2O was used to compute several thermodynamic properties that are compared to the results obtained by other workers from 5° to 40°C and 0 to 1000 bars.

UR - http://www.scopus.com/inward/record.url?scp=0001726893&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0001726893&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:0001726893

VL - 20

SP - 351

EP - 356

JO - Journal of Chemical & Engineering Data

JF - Journal of Chemical & Engineering Data

SN - 0021-9568

IS - 4

ER -