Solid-state photochemistry of cis-cinnamic acids: A competition between [2 + 2] addition and cis-trans isomerization

Giri Babu Veerakanellore; Burjor Captain; V. Ramamurthy

doi:10.1039/c6ce00682e

Solid-state photochemistry of cis-cinnamic acids: A competition between [2 + 2] addition and cis-trans isomerization

Giri Babu Veerakanellore, Burjor Captain, V. Ramamurthy

Chemistry

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

With three examples, we have established that cis-cinnamic acids can dimerize via a diradical intermediate in the crystalline state provided that the intermolecular distance is less than 4.2 Å. In the excited state of cis-isomers, C-C bond formation with an adjacent molecule competes with geometric isomerization.

Original language	English (US)
Pages (from-to)	4708-4712
Number of pages	5
Journal	CrystEngComm
Volume	18
Issue number	25
DOIs	https://doi.org/10.1039/c6ce00682e
State	Published - 2016

ASJC Scopus subject areas

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

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10.1039/c6ce00682e

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title = "Solid-state photochemistry of cis-cinnamic acids: A competition between [2 + 2] addition and cis-trans isomerization",

abstract = "With three examples, we have established that cis-cinnamic acids can dimerize via a diradical intermediate in the crystalline state provided that the intermolecular distance is less than 4.2 {\AA}. In the excited state of cis-isomers, C-C bond formation with an adjacent molecule competes with geometric isomerization.",

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AU - Ramamurthy, V.

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AB - With three examples, we have established that cis-cinnamic acids can dimerize via a diradical intermediate in the crystalline state provided that the intermolecular distance is less than 4.2 Å. In the excited state of cis-isomers, C-C bond formation with an adjacent molecule competes with geometric isomerization.

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Solid-state photochemistry of cis-cinnamic acids: A competition between [2 + 2] addition and cis-trans isomerization

Abstract

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