Solid-state photochemistry of cis-cinnamic acids: A competition between [2 + 2] addition and cis-trans isomerization

Giri Babu Veerakanellore, Burjor Captain, V. Ramamurthy

Research output: Contribution to journalArticle

6 Scopus citations

Abstract

With three examples, we have established that cis-cinnamic acids can dimerize via a diradical intermediate in the crystalline state provided that the intermolecular distance is less than 4.2 Å. In the excited state of cis-isomers, C-C bond formation with an adjacent molecule competes with geometric isomerization.

Original languageEnglish (US)
Pages (from-to)4708-4712
Number of pages5
JournalCrystEngComm
Volume18
Issue number25
DOIs
StatePublished - Jan 1 2016

    Fingerprint

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

Cite this