Single-step conversion of dimethyl terephthalate into cyclohexanedimethanol with Ru5PtSn, a trimetallic nanoparticle catalyst

Ana B. Hungria, Robert Raja, Richard D. Adams, Burjor Captain, John Meurig Thomas, Paul A. Midgley, Vladimir Golovko, Brian F G Johnson

Research output: Contribution to journal › Article

113 Citations (Scopus)

Abstract

Highly active and selective: A supported Ru5PtSn nanoparticle cluster (the picture shows an axial projection of a tomogram), prepared from the carbonyl cluster [PtRu5(CO)15(μ-SnPh 2)(μ6-C)], is an excellent catalyst in the single-step hydrogenation of dimethyl terephthalate to cyclohexanedimethanol under mild conditions (100°C, 20 bar H2). (Figure Presented).

Original languageEnglish
Pages (from-to)4782-4785
Number of pages4
JournalAngewandte Chemie - International Edition
Volume45
Issue number29
DOIs
StatePublished - Jul 17 2006
Externally publishedYes

Fingerprint

Carbon Monoxide
Hydrogenation
Nanoparticles
Catalysts
1,4-cyclohexanedimethanol
dimethyl 4-phthalate

Keywords

  • Electron microscopy
  • Heterogeneous catalysis
  • Hydrogenation
  • Nanoparticles
  • Tomography

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Single-step conversion of dimethyl terephthalate into cyclohexanedimethanol with Ru5PtSn, a trimetallic nanoparticle catalyst. / Hungria, Ana B.; Raja, Robert; Adams, Richard D.; Captain, Burjor; Thomas, John Meurig; Midgley, Paul A.; Golovko, Vladimir; Johnson, Brian F G.

In: Angewandte Chemie - International Edition, Vol. 45, No. 29, 17.07.2006, p. 4782-4785.

Research output: Contribution to journal › Article

Hungria, AB, Raja, R, Adams, RD, Captain, B, Thomas, JM, Midgley, PA, Golovko, V & Johnson, BFG 2006, 'Single-step conversion of dimethyl terephthalate into cyclohexanedimethanol with Ru5PtSn, a trimetallic nanoparticle catalyst', Angewandte Chemie - International Edition, vol. 45, no. 29, pp. 4782-4785. https://doi.org/10.1002/anie.200600359
Hungria AB, Raja R, Adams RD, Captain B, Thomas JM, Midgley PA et al. Single-step conversion of dimethyl terephthalate into cyclohexanedimethanol with Ru5PtSn, a trimetallic nanoparticle catalyst. Angewandte Chemie - International Edition. 2006 Jul 17;45(29):4782-4785. https://doi.org/10.1002/anie.200600359
Hungria, Ana B. ; Raja, Robert ; Adams, Richard D. ; Captain, Burjor ; Thomas, John Meurig ; Midgley, Paul A. ; Golovko, Vladimir ; Johnson, Brian F G. / Single-step conversion of dimethyl terephthalate into cyclohexanedimethanol with Ru5PtSn, a trimetallic nanoparticle catalyst. In: Angewandte Chemie - International Edition. 2006 ; Vol. 45, No. 29. pp. 4782-4785.
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