Single-step conversion of dimethyl terephthalate into cyclohexanedimethanol with Ru5PtSn, a trimetallic nanoparticle catalyst

Ana B. Hungria; Robert Raja; Richard D. Adams; Burjor Captain; John Meurig Thomas; Paul A. Midgley; Vladimir Golovko; Brian F.G. Johnson

doi:10.1002/anie.200600359

Single-step conversion of dimethyl terephthalate into cyclohexanedimethanol with Ru₅PtSn, a trimetallic nanoparticle catalyst

Ana B. Hungria, Robert Raja, Richard D. Adams, Burjor Captain, John Meurig Thomas, Paul A. Midgley, Vladimir Golovko, Brian F.G. Johnson

Research output: Contribution to journal › Article › peer-review

124 Scopus citations

Abstract

Highly active and selective: A supported Ru₅PtSn nanoparticle cluster (the picture shows an axial projection of a tomogram), prepared from the carbonyl cluster [PtRu₅(CO)₁₅(μ-SnPh ₂)(μ₆-C)], is an excellent catalyst in the single-step hydrogenation of dimethyl terephthalate to cyclohexanedimethanol under mild conditions (100°C, 20 bar H₂). (Figure Presented).

Original language	English (US)
Pages (from-to)	4782-4785
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	45
Issue number	29
DOIs	https://doi.org/10.1002/anie.200600359
State	Published - Jul 17 2006
Externally published	Yes

Keywords

Electron microscopy
Heterogeneous catalysis
Hydrogenation
Nanoparticles
Tomography

ASJC Scopus subject areas

Chemistry(all)

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10.1002/anie.200600359

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Single-step conversion of dimethyl terephthalate into cyclohexanedimethanol with Ru₅PtSn, a trimetallic nanoparticle catalyst. / Hungria, Ana B.; Raja, Robert; Adams, Richard D.; Captain, Burjor; Thomas, John Meurig; Midgley, Paul A.; Golovko, Vladimir; Johnson, Brian F.G.

In: Angewandte Chemie - International Edition, Vol. 45, No. 29, 17.07.2006, p. 4782-4785.

Research output: Contribution to journal › Article › peer-review

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abstract = "Highly active and selective: A supported Ru5PtSn nanoparticle cluster (the picture shows an axial projection of a tomogram), prepared from the carbonyl cluster [PtRu5(CO)15(μ-SnPh 2)(μ6-C)], is an excellent catalyst in the single-step hydrogenation of dimethyl terephthalate to cyclohexanedimethanol under mild conditions (100°C, 20 bar H2). (Figure Presented).",

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AU - Thomas, John Meurig

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AU - Golovko, Vladimir

AU - Johnson, Brian F.G.

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