Selective benzylic C-H activation of solvent toluene and m-xylene by an iron-tin cluster complex: Fe2(μ-SnBu2t)2(CO)8

Lei Zhu, Veeranna Yempally, Derek Isrow, Perry J. Pellechia, Burjor Captain

Research output: Contribution to journalArticle

17 Citations (Scopus)

Abstract

The bimetallic cluster complex Fe2(μ-SnBu2t)2(CO)8, 1, selectively activates the benzylic C-H bond in solvent toluene at reflux conditions to afford the complex Fe2[μ-SnBut(CH2Ph)]2(CO)8, 3, where two of the But groups in 1 have been replaced with benzyl groups. Similarly 1 also activates the benzylic C-H bond in solvent m-xylene to yield complexes Fe2[μ-SnBut(m-CH2PhMe)]2(CO)8, 4, Fe2[μ-SnBut(m-CH2PhMe)][μ-Sn(m-CH2PhMe)2](CO)8, 5, and Fe2[μ-Sn(m-CH2PhMe)2]2(CO)8, 6, where two, three and four of the But groups in 1 have been replaced by m-tolyl groups, respectively. A mechanism based on a radical pathway is proposed for the C-H activation by 1.

Original languageEnglish
Pages (from-to)1-5
Number of pages5
JournalJournal of Organometallic Chemistry
Volume695
Issue number1
DOIs
StatePublished - Jan 1 2010

Fingerprint

Tin
Toluene
xylene
Carbon Monoxide
Xylene
toluene
tin
Iron
Chemical activation
activation
iron
3-xylene

Keywords

  • Bimetallic cluster
  • C-H activation
  • Iron
  • Radical mechanism
  • Tin

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Organic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Chemistry
  • Biochemistry

Cite this

Selective benzylic C-H activation of solvent toluene and m-xylene by an iron-tin cluster complex : Fe2(μ-SnBu2t)2(CO)8. / Zhu, Lei; Yempally, Veeranna; Isrow, Derek; Pellechia, Perry J.; Captain, Burjor.

In: Journal of Organometallic Chemistry, Vol. 695, No. 1, 01.01.2010, p. 1-5.

Research output: Contribution to journalArticle

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abstract = "The bimetallic cluster complex Fe2(μ-SnBu2t)2(CO)8, 1, selectively activates the benzylic C-H bond in solvent toluene at reflux conditions to afford the complex Fe2[μ-SnBut(CH2Ph)]2(CO)8, 3, where two of the But groups in 1 have been replaced with benzyl groups. Similarly 1 also activates the benzylic C-H bond in solvent m-xylene to yield complexes Fe2[μ-SnBut(m-CH2PhMe)]2(CO)8, 4, Fe2[μ-SnBut(m-CH2PhMe)][μ-Sn(m-CH2PhMe)2](CO)8, 5, and Fe2[μ-Sn(m-CH2PhMe)2]2(CO)8, 6, where two, three and four of the But groups in 1 have been replaced by m-tolyl groups, respectively. A mechanism based on a radical pathway is proposed for the C-H activation by 1.",
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