Abstract
(Chemical Equation Presented) Pretty vacant: The unsymmetrical complex 1 contains one saturated 18-electron rhenium atom and one unsaturated 16-electron rhenium atom with a vacant coordination site. CO and NCMe can add to 1 to yield complexes in which both metal atoms have 18-electron configurations. Surprisingly, the added ligands are coordinated to the metal atom in 1 that originally had the 18-electron configuration.
Original language | English (US) |
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Pages (from-to) | 5714-5716 |
Number of pages | 3 |
Journal | Angewandte Chemie - International Edition |
Volume | 46 |
Issue number | 30 |
DOIs | |
State | Published - Aug 3 2007 |
Externally published | Yes |
Keywords
- Ligand addition
- Phosphorus
- Rhenium
- Structure elucidation
ASJC Scopus subject areas
- Chemistry(all)