Saturated versus unsaturated: Ligand addition to the saturated metal site in an unsaturated binuclear metal complex

Richard D. Adams; Burjor Captain

doi:10.1002/anie.200701370

Saturated versus unsaturated: Ligand addition to the saturated metal site in an unsaturated binuclear metal complex

Richard D. Adams, Burjor Captain

Research output: Contribution to journal › Article

5 Scopus citations

Abstract

(Chemical Equation Presented) Pretty vacant: The unsymmetrical complex 1 contains one saturated 18-electron rhenium atom and one unsaturated 16-electron rhenium atom with a vacant coordination site. CO and NCMe can add to 1 to yield complexes in which both metal atoms have 18-electron configurations. Surprisingly, the added ligands are coordinated to the metal atom in 1 that originally had the 18-electron configuration.

Original language	English (US)
Pages (from-to)	5714-5716
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	46
Issue number	30
DOIs	https://doi.org/10.1002/anie.200701370
State	Published - Aug 3 2007
Externally published	Yes

Keywords

Ligand addition
Phosphorus
Rhenium
Structure elucidation

ASJC Scopus subject areas

Chemistry(all)

Access to Document

10.1002/anie.200701370

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Adams, R. D., & Captain, B. (2007). Saturated versus unsaturated: Ligand addition to the saturated metal site in an unsaturated binuclear metal complex. Angewandte Chemie - International Edition, 46(30), 5714-5716. https://doi.org/10.1002/anie.200701370

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AU - Captain, Burjor

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AB - (Chemical Equation Presented) Pretty vacant: The unsymmetrical complex 1 contains one saturated 18-electron rhenium atom and one unsaturated 16-electron rhenium atom with a vacant coordination site. CO and NCMe can add to 1 to yield complexes in which both metal atoms have 18-electron configurations. Surprisingly, the added ligands are coordinated to the metal atom in 1 that originally had the 18-electron configuration.

KW - Ligand addition

KW - Phosphorus

KW - Rhenium

KW - Structure elucidation

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