Abstract
(Chemical Equation Presented) Pretty vacant: The unsymmetrical complex 1 contains one saturated 18-electron rhenium atom and one unsaturated 16-electron rhenium atom with a vacant coordination site. CO and NCMe can add to 1 to yield complexes in which both metal atoms have 18-electron configurations. Surprisingly, the added ligands are coordinated to the metal atom in 1 that originally had the 18-electron configuration.
| Original language | English |
|---|---|
| Pages (from-to) | 5714-5716 |
| Number of pages | 3 |
| Journal | Angewandte Chemie - International Edition |
| Volume | 46 |
| Issue number | 30 |
| DOIs | |
| State | Published - Aug 3 2007 |
| Externally published | Yes |
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Keywords
- Ligand addition
- Phosphorus
- Rhenium
- Structure elucidation
ASJC Scopus subject areas
- Chemistry(all)
Cite this
Saturated versus unsaturated : Ligand addition to the saturated metal site in an unsaturated binuclear metal complex. / Adams, Richard D.; Captain, Burjor.
In: Angewandte Chemie - International Edition, Vol. 46, No. 30, 03.08.2007, p. 5714-5716.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Saturated versus unsaturated
T2 - Ligand addition to the saturated metal site in an unsaturated binuclear metal complex
AU - Adams, Richard D.
AU - Captain, Burjor
PY - 2007/8/3
Y1 - 2007/8/3
N2 - (Chemical Equation Presented) Pretty vacant: The unsymmetrical complex 1 contains one saturated 18-electron rhenium atom and one unsaturated 16-electron rhenium atom with a vacant coordination site. CO and NCMe can add to 1 to yield complexes in which both metal atoms have 18-electron configurations. Surprisingly, the added ligands are coordinated to the metal atom in 1 that originally had the 18-electron configuration.
AB - (Chemical Equation Presented) Pretty vacant: The unsymmetrical complex 1 contains one saturated 18-electron rhenium atom and one unsaturated 16-electron rhenium atom with a vacant coordination site. CO and NCMe can add to 1 to yield complexes in which both metal atoms have 18-electron configurations. Surprisingly, the added ligands are coordinated to the metal atom in 1 that originally had the 18-electron configuration.
KW - Ligand addition
KW - Phosphorus
KW - Rhenium
KW - Structure elucidation
UR - http://www.scopus.com/inward/record.url?scp=34547420194&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=34547420194&partnerID=8YFLogxK
U2 - 10.1002/anie.200701370
DO - 10.1002/anie.200701370
M3 - Article
C2 - 17600807
AN - SCOPUS:34547420194
VL - 46
SP - 5714
EP - 5716
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
SN - 1433-7851
IS - 30
ER -