Saturated versus unsaturated: Ligand addition to the saturated metal site in an unsaturated binuclear metal complex

Richard D. Adams, Burjor Captain

Research output: Contribution to journalArticle

5 Scopus citations

Abstract

(Chemical Equation Presented) Pretty vacant: The unsymmetrical complex 1 contains one saturated 18-electron rhenium atom and one unsaturated 16-electron rhenium atom with a vacant coordination site. CO and NCMe can add to 1 to yield complexes in which both metal atoms have 18-electron configurations. Surprisingly, the added ligands are coordinated to the metal atom in 1 that originally had the 18-electron configuration.

Original languageEnglish (US)
Pages (from-to)5714-5716
Number of pages3
JournalAngewandte Chemie - International Edition
Volume46
Issue number30
DOIs
StatePublished - Aug 3 2007

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Keywords

  • Ligand addition
  • Phosphorus
  • Rhenium
  • Structure elucidation

ASJC Scopus subject areas

  • Chemistry(all)

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