Reversible hydrogen activation by the Pt complex Pt(SntBu 3)2(CNtBu)2

Veeranna Yempally, Lei Zhu, Burjor Captain

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

The new platinum complex Pt(SntBu3) 2(CNtBu)2(H)2, 1, was obtained in 32% yield from the reaction of Pt(COD)2 with tBu 3SnH and CNtBu at room temperature. Compound 1 is a mononuclear 18 electron platinum complex in an octahedral geometry which contains two SntBu3's, two CNtBu's, and two hydride ligands. The two hydride ligands in 1 can be eliminated, both in solution and in the solid state, to yield the 16 electron complex Pt(Sn tBu3)2(CNtBu)2, 2. Compound 2 reacts with hydrogen at room temperature in solution and in the solid state to regenerate 1.

Original languageEnglish
Pages (from-to)7238-7240
Number of pages3
JournalInorganic Chemistry
Volume49
Issue number16
DOIs
StatePublished - Aug 16 2010

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Platinum
Hydrides
hydrides
Hydrogen
platinum
Chemical activation
activation
Ligands
solid state
ligands
crack opening displacement
Electrons
room temperature
hydrogen
electrons
Temperature
Geometry
geometry

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Physical and Theoretical Chemistry

Cite this

Reversible hydrogen activation by the Pt complex Pt(SntBu 3)2(CNtBu)2. / Yempally, Veeranna; Zhu, Lei; Captain, Burjor.

In: Inorganic Chemistry, Vol. 49, No. 16, 16.08.2010, p. 7238-7240.

Research output: Contribution to journalArticle

Yempally, Veeranna ; Zhu, Lei ; Captain, Burjor. / Reversible hydrogen activation by the Pt complex Pt(SntBu 3)2(CNtBu)2. In: Inorganic Chemistry. 2010 ; Vol. 49, No. 16. pp. 7238-7240.
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