Abstract
The new platinum complex Pt(SntBu3) 2(CNtBu)2(H)2, 1, was obtained in 32% yield from the reaction of Pt(COD)2 with tBu 3SnH and CNtBu at room temperature. Compound 1 is a mononuclear 18 electron platinum complex in an octahedral geometry which contains two SntBu3's, two CNtBu's, and two hydride ligands. The two hydride ligands in 1 can be eliminated, both in solution and in the solid state, to yield the 16 electron complex Pt(Sn tBu3)2(CNtBu)2, 2. Compound 2 reacts with hydrogen at room temperature in solution and in the solid state to regenerate 1.
| Original language | English |
|---|---|
| Pages (from-to) | 7238-7240 |
| Number of pages | 3 |
| Journal | Inorganic Chemistry |
| Volume | 49 |
| Issue number | 16 |
| DOIs | |
| State | Published - Aug 16 2010 |
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ASJC Scopus subject areas
- Inorganic Chemistry
- Physical and Theoretical Chemistry
Cite this
Reversible hydrogen activation by the Pt complex Pt(SntBu 3)2(CNtBu)2. / Yempally, Veeranna; Zhu, Lei; Captain, Burjor.
In: Inorganic Chemistry, Vol. 49, No. 16, 16.08.2010, p. 7238-7240.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Reversible hydrogen activation by the Pt complex Pt(SntBu 3)2(CNtBu)2
AU - Yempally, Veeranna
AU - Zhu, Lei
AU - Captain, Burjor
PY - 2010/8/16
Y1 - 2010/8/16
N2 - The new platinum complex Pt(SntBu3) 2(CNtBu)2(H)2, 1, was obtained in 32% yield from the reaction of Pt(COD)2 with tBu 3SnH and CNtBu at room temperature. Compound 1 is a mononuclear 18 electron platinum complex in an octahedral geometry which contains two SntBu3's, two CNtBu's, and two hydride ligands. The two hydride ligands in 1 can be eliminated, both in solution and in the solid state, to yield the 16 electron complex Pt(Sn tBu3)2(CNtBu)2, 2. Compound 2 reacts with hydrogen at room temperature in solution and in the solid state to regenerate 1.
AB - The new platinum complex Pt(SntBu3) 2(CNtBu)2(H)2, 1, was obtained in 32% yield from the reaction of Pt(COD)2 with tBu 3SnH and CNtBu at room temperature. Compound 1 is a mononuclear 18 electron platinum complex in an octahedral geometry which contains two SntBu3's, two CNtBu's, and two hydride ligands. The two hydride ligands in 1 can be eliminated, both in solution and in the solid state, to yield the 16 electron complex Pt(Sn tBu3)2(CNtBu)2, 2. Compound 2 reacts with hydrogen at room temperature in solution and in the solid state to regenerate 1.
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UR - http://www.scopus.com/inward/citedby.url?scp=77955497991&partnerID=8YFLogxK
U2 - 10.1021/ic101025h
DO - 10.1021/ic101025h
M3 - Article
C2 - 20690734
AN - SCOPUS:77955497991
VL - 49
SP - 7238
EP - 7240
JO - Inorganic Chemistry
JF - Inorganic Chemistry
SN - 0020-1669
IS - 16
ER -