Abstract
The cucurbit[8]uril (CB8) templation strategy that is known to yield stereoselective photodimers of organic olefins has been extended to substituted butadienes. By virtue of its strong binding interactions with guests the rigid cavity of CB8 is capable of preorienting the diene guests to result in greater yields of stereoselective photodimers upon irradiation. The symmetry of the butadiene monomers influences the relative arrangement of the monomers in complexes leading to the observed product selectivity.
| Original language | English |
|---|---|
| Pages (from-to) | 9219-9222 |
| Number of pages | 4 |
| Journal | Organic and Biomolecular Chemistry |
| Volume | 10 |
| Issue number | 46 |
| DOIs | |
| State | Published - Dec 14 2012 |
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ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Organic Chemistry
- Biochemistry
Cite this
Regioselective photodimerization of pyridyl-butadienes within cucurbit[8]uril cavities. / Maddipatla, Murthy V S N; Pattabiraman, Mahesh; Natarajan, Arunkumar; Srivastav, Karan; Mague, Joel T.; Ramamurthy, Vaidhyanathan.
In: Organic and Biomolecular Chemistry, Vol. 10, No. 46, 14.12.2012, p. 9219-9222.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Regioselective photodimerization of pyridyl-butadienes within cucurbit[8]uril cavities
AU - Maddipatla, Murthy V S N
AU - Pattabiraman, Mahesh
AU - Natarajan, Arunkumar
AU - Srivastav, Karan
AU - Mague, Joel T.
AU - Ramamurthy, Vaidhyanathan
PY - 2012/12/14
Y1 - 2012/12/14
N2 - The cucurbit[8]uril (CB8) templation strategy that is known to yield stereoselective photodimers of organic olefins has been extended to substituted butadienes. By virtue of its strong binding interactions with guests the rigid cavity of CB8 is capable of preorienting the diene guests to result in greater yields of stereoselective photodimers upon irradiation. The symmetry of the butadiene monomers influences the relative arrangement of the monomers in complexes leading to the observed product selectivity.
AB - The cucurbit[8]uril (CB8) templation strategy that is known to yield stereoselective photodimers of organic olefins has been extended to substituted butadienes. By virtue of its strong binding interactions with guests the rigid cavity of CB8 is capable of preorienting the diene guests to result in greater yields of stereoselective photodimers upon irradiation. The symmetry of the butadiene monomers influences the relative arrangement of the monomers in complexes leading to the observed product selectivity.
UR - http://www.scopus.com/inward/record.url?scp=84868649472&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84868649472&partnerID=8YFLogxK
U2 - 10.1039/c2ob26743h
DO - 10.1039/c2ob26743h
M3 - Article
C2 - 23103970
AN - SCOPUS:84868649472
VL - 10
SP - 9219
EP - 9222
JO - Organic and Biomolecular Chemistry
JF - Organic and Biomolecular Chemistry
SN - 1477-0520
IS - 46
ER -