Regioselective photodimerization of pyridyl-butadienes within cucurbit[8]uril cavities

Murthy V S N Maddipatla, Mahesh Pattabiraman, Arunkumar Natarajan, Karan Srivastav, Joel T. Mague, Vaidhyanathan Ramamurthy

Research output: Contribution to journalArticle

16 Citations (Scopus)

Abstract

The cucurbit[8]uril (CB8) templation strategy that is known to yield stereoselective photodimers of organic olefins has been extended to substituted butadienes. By virtue of its strong binding interactions with guests the rigid cavity of CB8 is capable of preorienting the diene guests to result in greater yields of stereoselective photodimers upon irradiation. The symmetry of the butadiene monomers influences the relative arrangement of the monomers in complexes leading to the observed product selectivity.

Original languageEnglish
Pages (from-to)9219-9222
Number of pages4
JournalOrganic and Biomolecular Chemistry
Volume10
Issue number46
DOIs
StatePublished - Dec 14 2012

Fingerprint

Butadienes
Alkenes
butadiene
monomers
Monomers
cavities
dienes
alkenes
selectivity
Irradiation
irradiation
symmetry
products
interactions
cucurbit(8)uril
1,3-butadiene

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Biochemistry

Cite this

Maddipatla, M. V. S. N., Pattabiraman, M., Natarajan, A., Srivastav, K., Mague, J. T., & Ramamurthy, V. (2012). Regioselective photodimerization of pyridyl-butadienes within cucurbit[8]uril cavities. Organic and Biomolecular Chemistry, 10(46), 9219-9222. https://doi.org/10.1039/c2ob26743h

Regioselective photodimerization of pyridyl-butadienes within cucurbit[8]uril cavities. / Maddipatla, Murthy V S N; Pattabiraman, Mahesh; Natarajan, Arunkumar; Srivastav, Karan; Mague, Joel T.; Ramamurthy, Vaidhyanathan.

In: Organic and Biomolecular Chemistry, Vol. 10, No. 46, 14.12.2012, p. 9219-9222.

Research output: Contribution to journalArticle

Maddipatla, MVSN, Pattabiraman, M, Natarajan, A, Srivastav, K, Mague, JT & Ramamurthy, V 2012, 'Regioselective photodimerization of pyridyl-butadienes within cucurbit[8]uril cavities', Organic and Biomolecular Chemistry, vol. 10, no. 46, pp. 9219-9222. https://doi.org/10.1039/c2ob26743h
Maddipatla, Murthy V S N ; Pattabiraman, Mahesh ; Natarajan, Arunkumar ; Srivastav, Karan ; Mague, Joel T. ; Ramamurthy, Vaidhyanathan. / Regioselective photodimerization of pyridyl-butadienes within cucurbit[8]uril cavities. In: Organic and Biomolecular Chemistry. 2012 ; Vol. 10, No. 46. pp. 9219-9222.
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