Redox active, hybrid dendrimers containing Fréchet- and Newkome-type blocks

Wei Wang; Hao Sun; Angel E. Kaifer

doi:10.1021/ol0708525

Redox active, hybrid dendrimers containing Fréchet- and Newkome-type blocks

Wei Wang, Hao Sun, Angel E. Kaifer

Chemistry

Research output: Contribution to journal › Article › peer-review

26 Scopus citations

Abstract

Equation Presented A new series of dendrimers was prepared by covalently attaching a Newkome dendron, a Freenet dendron, and a redox active, aminoferrocene group to a central triazine core. Growth of the Newkome dendron has a more pronounced effect on the half-wave potential for the one-electron oxidation of the ferrocene residue than growth of the Fréchet dendron. All dendrimers show reversible or quasireversible voltammetric behavior at scan rates in the range 0.10-2.0 V s ^-1.

Original language	English (US)
Pages (from-to)	2657-2660
Number of pages	4
Journal	Organic letters
Volume	9
Issue number	14
DOIs	https://doi.org/10.1021/ol0708525
State	Published - Jul 5 2007

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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abstract = "Equation Presented A new series of dendrimers was prepared by covalently attaching a Newkome dendron, a Freenet dendron, and a redox active, aminoferrocene group to a central triazine core. Growth of the Newkome dendron has a more pronounced effect on the half-wave potential for the one-electron oxidation of the ferrocene residue than growth of the Fr{\'e}chet dendron. All dendrimers show reversible or quasireversible voltammetric behavior at scan rates in the range 0.10-2.0 V s -1.",

author = "Wei Wang and Hao Sun and Kaifer, {Angel E.}",

year = "2007",

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T1 - Redox active, hybrid dendrimers containing Fréchet- and Newkome-type blocks

AU - Wang, Wei

AU - Sun, Hao

AU - Kaifer, Angel E.

PY - 2007/7/5

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N2 - Equation Presented A new series of dendrimers was prepared by covalently attaching a Newkome dendron, a Freenet dendron, and a redox active, aminoferrocene group to a central triazine core. Growth of the Newkome dendron has a more pronounced effect on the half-wave potential for the one-electron oxidation of the ferrocene residue than growth of the Fréchet dendron. All dendrimers show reversible or quasireversible voltammetric behavior at scan rates in the range 0.10-2.0 V s -1.

AB - Equation Presented A new series of dendrimers was prepared by covalently attaching a Newkome dendron, a Freenet dendron, and a redox active, aminoferrocene group to a central triazine core. Growth of the Newkome dendron has a more pronounced effect on the half-wave potential for the one-electron oxidation of the ferrocene residue than growth of the Fréchet dendron. All dendrimers show reversible or quasireversible voltammetric behavior at scan rates in the range 0.10-2.0 V s -1.

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