Reactions in elastomeric nanoreactors reveal the role of force on the kinetics of the Huisgen reaction on surfaces

Xu Han; Shudan Bian; Yong Liang; K. N. Houk; Adam B. Braunschweig

doi:10.1021/ja504137u

Reactions in elastomeric nanoreactors reveal the role of force on the kinetics of the Huisgen reaction on surfaces

Xu Han, Shudan Bian, Yong Liang, K. N. Houk, Adam B. Braunschweig

Chemistry

Research output: Contribution to journal › Article › peer-review

23 Scopus citations

Abstract

The force dependence of the copper-free Huisgen cycloaddition between an alkyne and a surface-bound azide was examined in elastomeric nanoreactors. These studies revealed that pressure and chain length are critical factors that determine the reaction rate. These experiments demonstrate the central role of pressure and surface structure on interfacial processes that are increasingly important in biology, materials science, and nanotechnology.

Original language	English (US)
Pages (from-to)	10553-10556
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	136
Issue number	30
DOIs	https://doi.org/10.1021/ja504137u
State	Published - Jul 30 2014

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

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abstract = "The force dependence of the copper-free Huisgen cycloaddition between an alkyne and a surface-bound azide was examined in elastomeric nanoreactors. These studies revealed that pressure and chain length are critical factors that determine the reaction rate. These experiments demonstrate the central role of pressure and surface structure on interfacial processes that are increasingly important in biology, materials science, and nanotechnology.",

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AU - Braunschweig, Adam B.

PY - 2014/7/30

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N2 - The force dependence of the copper-free Huisgen cycloaddition between an alkyne and a surface-bound azide was examined in elastomeric nanoreactors. These studies revealed that pressure and chain length are critical factors that determine the reaction rate. These experiments demonstrate the central role of pressure and surface structure on interfacial processes that are increasingly important in biology, materials science, and nanotechnology.

AB - The force dependence of the copper-free Huisgen cycloaddition between an alkyne and a surface-bound azide was examined in elastomeric nanoreactors. These studies revealed that pressure and chain length are critical factors that determine the reaction rate. These experiments demonstrate the central role of pressure and surface structure on interfacial processes that are increasingly important in biology, materials science, and nanotechnology.

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Reactions in elastomeric nanoreactors reveal the role of force on the kinetics of the Huisgen reaction on surfaces

Abstract

ASJC Scopus subject areas

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