Abstract
A new heterometallic electroactive compound having the ferrocenyl moiety attached to the platinum atom through an amidine functionality has been prepared via Pt(ii)-mediated nucleophilic addition of β-aminoethylferrocene to a benzonitrile ligand. This neutral receptor shows remarkable electrochemical anion-sensing redox response to H 2PO 4 -.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 10398-10400 |
| Number of pages | 3 |
| Journal | Chemical Communications |
| Volume | 47 |
| Issue number | 37 |
| DOIs | |
| State | Published - Oct 7 2011 |
ASJC Scopus subject areas
- Catalysis
- Electronic, Optical and Magnetic Materials
- Ceramics and Composites
- Chemistry(all)
- Surfaces, Coatings and Films
- Metals and Alloys
- Materials Chemistry
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Nieto, D., González-Vadillo, A. M., Bruña, S., Pastor, C. J., Kaifer, A. E., & Cuadrado, I. (2011). Pt(II)-activated coupling of aminoethylferrocene with benzonitrile. A facile access route to a new redox-active bis(ferrocenyl-amidine) anion sensor. Chemical Communications, 47(37), 10398-10400. https://doi.org/10.1039/c1cc13704b