Pt(II)-activated coupling of aminoethylferrocene with benzonitrile. A facile access route to a new redox-active bis(ferrocenyl-amidine) anion sensor

Daniel Nieto; Ana M. González-Vadillo; Sonia Bruña; César J. Pastor; Angel E. Kaifer; Isabel Cuadrado

doi:10.1039/c1cc13704b

Pt(II)-activated coupling of aminoethylferrocene with benzonitrile. A facile access route to a new redox-active bis(ferrocenyl-amidine) anion sensor

Daniel Nieto, Ana M. González-Vadillo, Sonia Bruña, César J. Pastor, Angel E. Kaifer, Isabel Cuadrado

Chemistry

Research output: Contribution to journal › Article › peer-review

18 Scopus citations

Abstract

A new heterometallic electroactive compound having the ferrocenyl moiety attached to the platinum atom through an amidine functionality has been prepared via Pt(ii)-mediated nucleophilic addition of β-aminoethylferrocene to a benzonitrile ligand. This neutral receptor shows remarkable electrochemical anion-sensing redox response to H ₂PO ₄ ^-.

Original language	English (US)
Pages (from-to)	10398-10400
Number of pages	3
Journal	Chemical Communications
Volume	47
Issue number	37
DOIs	https://doi.org/10.1039/c1cc13704b
State	Published - Oct 7 2011

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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Pt(II)-activated coupling of aminoethylferrocene with benzonitrile. A facile access route to a new redox-active bis(ferrocenyl-amidine) anion sensor. / Nieto, Daniel; González-Vadillo, Ana M.; Bruña, Sonia; Pastor, César J.; Kaifer, Angel E.; Cuadrado, Isabel.

In: Chemical Communications, Vol. 47, No. 37, 07.10.2011, p. 10398-10400.

Research output: Contribution to journal › Article › peer-review

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abstract = "A new heterometallic electroactive compound having the ferrocenyl moiety attached to the platinum atom through an amidine functionality has been prepared via Pt(ii)-mediated nucleophilic addition of β-aminoethylferrocene to a benzonitrile ligand. This neutral receptor shows remarkable electrochemical anion-sensing redox response to H 2PO 4 -.",

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