Abstract
The slow approach to equilibrium concentration indicative of non-Fickian diffusion in polymer composites necessitates experimental time frames which are often of limited feasibility. As a result, experimental studies are terminated prematurely due to time constraints or incorrect identification of equilibrium. Here, the three-dimensional anisotropic diffusion behaviors of six-, twelve-, and forty-ply quartz-reinforced bismaleimide laminates are quantified through a 5-year, full-immersion gravimetric absorption study. The applicability of the three-dimensional hindered diffusion model is investigated, while projections of future absorption behavior made at 21 months are revisited in light of 3 years of additional data. The mathematical equivalency of the hindered diffusion model and a diffusion–relaxation model under certain conditions is discussed. Moisture content rises continuously throughout the 5-year experiment for all samples. In the six-ply case, the standard termination criterion for the equilibrium condition is met before 6 months and 1.38 % moisture content by weight. Actual moisture content reaches 1.56 % after 5 years. The hindered diffusion model and associated forward projections of moisture content are found to conform well to experimental results.
Original language | English (US) |
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Pages (from-to) | 845-853 |
Number of pages | 9 |
Journal | Journal of Materials Science |
Volume | 51 |
Issue number | 2 |
DOIs | |
State | Published - Jan 1 2016 |
Keywords
- Bismaleimide
- Hindered diffusion
- Laminate
- Moisture absorption
ASJC Scopus subject areas
- Materials Science(all)
- Mechanics of Materials
- Mechanical Engineering