Abstract
In quarantine: Nitroxide spin probes are encapsulated by hexameric resorcinarene molecular capsules in dichloromethane solutions (see picture). A substantial reduction in the tumbling rates occurs upon encapsulation of two cationic probes and one neutral probe. As the molecular volume of the probe increases, the tumbling rate of the probe reflects the overall tumbling rate of the entire supramolecular assembly.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 5337-5340 |
| Number of pages | 4 |
| Journal | Angewandte Chemie - International Edition |
| Volume | 48 |
| Issue number | 29 |
| DOIs | |
| State | Published - Jul 6 2009 |
Keywords
- Encapsulation
- Host-guest systems
- Nitrogen oxides
- Self-assembly
- Spin probes
ASJC Scopus subject areas
- Chemistry(all)
- Catalysis
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Cite this
Mileo, E., Yi, S., Bhattacharya, P., & Kaifer, A. E. (2009). Probing the inner space of resorcinarene molecular capsules with nitroxide guests. Angewandte Chemie - International Edition, 48(29), 5337-5340. https://doi.org/10.1002/anie.200901272