Platinum-ruthenium cluster complexes from the reaction of Ru 3(CO)12 with Pt(PBut 3)2

Richard D. Adams; Erin M. Boswell; Burjor Captain; Lei Zhu

doi:10.1007/s10876-007-0166-1

Platinum-ruthenium cluster complexes from the reaction of Ru ₃(CO)₁₂ with Pt(PBu^t ₃)₂

Richard D. Adams, Erin M. Boswell, Burjor Captain, Lei Zhu

Research output: Contribution to journal › Article › peer-review

14 Scopus citations

Abstract

Three new platinum-ruthenium complexes: Pt₃Ru ₃(PBu^t ₃)₃(CO)₁₂, 8, Pt₅Ru₃(PBu^t ₃)₃(CO) ₁₂, 9 and PtRu₃(PBu^t ₃) ₂(CO)₈(μ₃-PBu^t)(μ-H) ₂, 10 were obtained from the reaction of Ru₃(CO) ₁₂ with Pt(PBu^t ₃)₂. Compound 8 was obtained from this reaction when conducted at 25 °C. Compounds 9 and 10 were obtained when the reaction was conducted at 68 °C. The structure of 8 consists of a central triangular cluster of three ruthenium atoms with one Pt(PBu^t ₃) group bridging each of the three Ru-Ru bonds. The structure of 9 consists of a capped pentagonal bipyramidal cluster of eight metal atoms that is formed formally by the addition of two platinum atoms to 8. The structure of 10 contains a triangular cluster of three ruthenium atoms with a Pt(PBu^t ₃) group bridging one of the Ru-Ru bonds. A t-butyl phosphido ligand formed by degradation of a molecule of PBu^t ₃ bridges the three ruthenium atoms.

Original language	English (US)
Pages (from-to)	121-132
Number of pages	12
Journal	Journal of Cluster Science
Volume	19
Issue number	1
DOIs	https://doi.org/10.1007/s10876-007-0166-1
State	Published - Mar 2008
Externally published	Yes

Keywords

Cluster growth
Platinum
Ruthenium

ASJC Scopus subject areas

Inorganic Chemistry

Access to Document

10.1007/s10876-007-0166-1

Cite this

@article{705001cd3ca540eb930b75777d2815b4,

title = "Platinum-ruthenium cluster complexes from the reaction of Ru 3(CO)12 with Pt(PBut 3)2",

abstract = "Three new platinum-ruthenium complexes: Pt3Ru 3(PBut 3)3(CO)12, 8, Pt5Ru3(PBut 3)3(CO) 12, 9 and PtRu3(PBut 3) 2(CO)8(μ3-PBut)(μ-H) 2, 10 were obtained from the reaction of Ru3(CO) 12 with Pt(PBut 3)2. Compound 8 was obtained from this reaction when conducted at 25 °C. Compounds 9 and 10 were obtained when the reaction was conducted at 68 °C. The structure of 8 consists of a central triangular cluster of three ruthenium atoms with one Pt(PBut 3) group bridging each of the three Ru-Ru bonds. The structure of 9 consists of a capped pentagonal bipyramidal cluster of eight metal atoms that is formed formally by the addition of two platinum atoms to 8. The structure of 10 contains a triangular cluster of three ruthenium atoms with a Pt(PBut 3) group bridging one of the Ru-Ru bonds. A t-butyl phosphido ligand formed by degradation of a molecule of PBut 3 bridges the three ruthenium atoms.",

keywords = "Cluster growth, Platinum, Ruthenium",

author = "Adams, {Richard D.} and Boswell, {Erin M.} and Burjor Captain and Lei Zhu",

note = "Funding Information: Acknowledgments This research was supported by the Office of Basic Energy Sciences of the U.S. Department of Energy under Grant No. DE-FG02-00ER14980, and the USC NanoCenter.",

year = "2008",

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AU - Adams, Richard D.

AU - Boswell, Erin M.

AU - Captain, Burjor

AU - Zhu, Lei

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Y1 - 2008/3

N2 - Three new platinum-ruthenium complexes: Pt3Ru 3(PBut 3)3(CO)12, 8, Pt5Ru3(PBut 3)3(CO) 12, 9 and PtRu3(PBut 3) 2(CO)8(μ3-PBut)(μ-H) 2, 10 were obtained from the reaction of Ru3(CO) 12 with Pt(PBut 3)2. Compound 8 was obtained from this reaction when conducted at 25 °C. Compounds 9 and 10 were obtained when the reaction was conducted at 68 °C. The structure of 8 consists of a central triangular cluster of three ruthenium atoms with one Pt(PBut 3) group bridging each of the three Ru-Ru bonds. The structure of 9 consists of a capped pentagonal bipyramidal cluster of eight metal atoms that is formed formally by the addition of two platinum atoms to 8. The structure of 10 contains a triangular cluster of three ruthenium atoms with a Pt(PBut 3) group bridging one of the Ru-Ru bonds. A t-butyl phosphido ligand formed by degradation of a molecule of PBut 3 bridges the three ruthenium atoms.

AB - Three new platinum-ruthenium complexes: Pt3Ru 3(PBut 3)3(CO)12, 8, Pt5Ru3(PBut 3)3(CO) 12, 9 and PtRu3(PBut 3) 2(CO)8(μ3-PBut)(μ-H) 2, 10 were obtained from the reaction of Ru3(CO) 12 with Pt(PBut 3)2. Compound 8 was obtained from this reaction when conducted at 25 °C. Compounds 9 and 10 were obtained when the reaction was conducted at 68 °C. The structure of 8 consists of a central triangular cluster of three ruthenium atoms with one Pt(PBut 3) group bridging each of the three Ru-Ru bonds. The structure of 9 consists of a capped pentagonal bipyramidal cluster of eight metal atoms that is formed formally by the addition of two platinum atoms to 8. The structure of 10 contains a triangular cluster of three ruthenium atoms with a Pt(PBut 3) group bridging one of the Ru-Ru bonds. A t-butyl phosphido ligand formed by degradation of a molecule of PBut 3 bridges the three ruthenium atoms.

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