Abstract
The hydride and PhC2H complexes, Ru5(CO)14(μ6-C)[Pt(PBut3)](μ-H)2, 2, and Ru5(CO)13(μ5-C)(PhC2H)[Pt(PBut3)], 3, were obtained from the reactions of Ru5(CO)15(C)[Pt(PBut3)], 1, with hydrogen and PhC2H, respectively. Styrene was formed catalytically when hydrogen and PhC2H were allowed to react with 3 in combination, and the complex Ru5(CO)12(μ5-C)[PtPBut3](PhC2H)(μ-H)2, 4, containing both hydrides and a PhC2H ligand was formed. The catalysis is promoted by the presence of the platinum atom in the complexes.
| Original language | English |
|---|---|
| Pages (from-to) | 3042-3043 |
| Number of pages | 2 |
| Journal | Journal of the American Chemical Society |
| Volume | 126 |
| Issue number | 10 |
| DOIs | |
| State | Published - Mar 17 2004 |
| Externally published | Yes |
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ASJC Scopus subject areas
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Cite this
Platinum Participation in the Hydrogenation of Phenylacetylene by Ru 5(CO)15(C)[Pt(PBut3)]. / Adams, Richard D.; Captain, Burjor; Zhu, Lei.
In: Journal of the American Chemical Society, Vol. 126, No. 10, 17.03.2004, p. 3042-3043.Research output: Contribution to journal › Article
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TY - JOUR
T1 - Platinum Participation in the Hydrogenation of Phenylacetylene by Ru 5(CO)15(C)[Pt(PBut3)]
AU - Adams, Richard D.
AU - Captain, Burjor
AU - Zhu, Lei
PY - 2004/3/17
Y1 - 2004/3/17
N2 - The hydride and PhC2H complexes, Ru5(CO)14(μ6-C)[Pt(PBut3)](μ-H)2, 2, and Ru5(CO)13(μ5-C)(PhC2H)[Pt(PBut3)], 3, were obtained from the reactions of Ru5(CO)15(C)[Pt(PBut3)], 1, with hydrogen and PhC2H, respectively. Styrene was formed catalytically when hydrogen and PhC2H were allowed to react with 3 in combination, and the complex Ru5(CO)12(μ5-C)[PtPBut3](PhC2H)(μ-H)2, 4, containing both hydrides and a PhC2H ligand was formed. The catalysis is promoted by the presence of the platinum atom in the complexes.
AB - The hydride and PhC2H complexes, Ru5(CO)14(μ6-C)[Pt(PBut3)](μ-H)2, 2, and Ru5(CO)13(μ5-C)(PhC2H)[Pt(PBut3)], 3, were obtained from the reactions of Ru5(CO)15(C)[Pt(PBut3)], 1, with hydrogen and PhC2H, respectively. Styrene was formed catalytically when hydrogen and PhC2H were allowed to react with 3 in combination, and the complex Ru5(CO)12(μ5-C)[PtPBut3](PhC2H)(μ-H)2, 4, containing both hydrides and a PhC2H ligand was formed. The catalysis is promoted by the presence of the platinum atom in the complexes.
UR - http://www.scopus.com/inward/record.url?scp=1642323525&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=1642323525&partnerID=8YFLogxK
U2 - 10.1021/ja049955y
DO - 10.1021/ja049955y
M3 - Article
C2 - 15012121
AN - SCOPUS:1642323525
VL - 126
SP - 3042
EP - 3043
JO - Journal of the American Chemical Society
JF - Journal of the American Chemical Society
SN - 0002-7863
IS - 10
ER -