Abstract
The hydride and PhC2H complexes, Ru5(CO)14(μ6-C)[Pt(PBut3)](μ-H)2, 2, and Ru5(CO)13(μ5-C)(PhC2H)[Pt(PBut3)], 3, were obtained from the reactions of Ru5(CO)15(C)[Pt(PBut3)], 1, with hydrogen and PhC2H, respectively. Styrene was formed catalytically when hydrogen and PhC2H were allowed to react with 3 in combination, and the complex Ru5(CO)12(μ5-C)[PtPBut3](PhC2H)(μ-H)2, 4, containing both hydrides and a PhC2H ligand was formed. The catalysis is promoted by the presence of the platinum atom in the complexes.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 3042-3043 |
| Number of pages | 2 |
| Journal | Journal of the American Chemical Society |
| Volume | 126 |
| Issue number | 10 |
| DOIs | |
| State | Published - Mar 17 2004 |
| Externally published | Yes |
ASJC Scopus subject areas
- Catalysis
- Chemistry(all)
- Biochemistry
- Colloid and Surface Chemistry
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Cite this
Adams, R. D., Captain, B., & Zhu, L. (2004). Platinum Participation in the Hydrogenation of Phenylacetylene by Ru 5(CO)15(C)[Pt(PBut3)]. Journal of the American Chemical Society, 126(10), 3042-3043. https://doi.org/10.1021/ja049955y