Photoisomerization of 2,3-diphenylcyclopropane-1-carboxylic acid derivatives

J. Sivaguru, Steffen Jockusch, Nicholas J. Turro, V. Ramamurthy

Research output: Contribution to journalArticle

13 Scopus citations

Abstract

Contrary to what is known about cis-1,2-diphenylcyclopropane and its derivatives, we find that they have triplet energies of ca. 311 kJ mol -1, do not undergo intersystem crossing upon direct excitation, undergo the less common adiabatic photoisomerization to the corresponding trans isomers, and show emission from excited 1,3-diradical intermediates.

Original languageEnglish (US)
Pages (from-to)1101-1106
Number of pages6
JournalPhotochemical and Photobiological Sciences
Volume2
Issue number11
DOIs
StatePublished - Nov 1 2003
Externally publishedYes

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry

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