Abstract
The photoreaction between C5H5Fe(CO)2Si(CH3)3 (I) and cyclohexyl isocyanide leads to the sequential replacement of both carbonyl groups by the isocyanide. Both the racemic monosubstituted product, C5H5Fe(CO)(C6H11NC)Si(CH3)3 (II) and the disubstituted product, C5H5Fe(C6H11NC)2Si(CH3)3 (III) have been isolated and characterized. Photoreaction between the disubstituted product III and C5H5Fe(CO)2Si(CH3)3 in a sealed tube gives the monosubstituted product, II. Thermal initiation of the above reactions failed. The disubstituted product III is stable under both the thermal and photochemical conditions used; thus, insertion of isocyanide into FeSi bond was observed not to occur.
| Original language | English |
|---|---|
| Pages (from-to) | 287-293 |
| Number of pages | 7 |
| Journal | Journal of Organometallic Chemistry |
| Volume | 152 |
| Issue number | 3 |
| DOIs | |
| State | Published - Jun 6 1978 |
| Externally published | Yes |
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ASJC Scopus subject areas
- Biochemistry
- Chemical Engineering (miscellaneous)
- Inorganic Chemistry
- Organic Chemistry
- Physical and Theoretical Chemistry
- Materials Science (miscellaneous)
- Materials Chemistry
Cite this
Photochemical reaction between cyclohexyl isocyanide and π-cyclopentadienyldicarbonyltrimethylsilyliron(II). / Chan, Tze Ming; Connolly, John W.; Hoff, Carl; Millich, Frank.
In: Journal of Organometallic Chemistry, Vol. 152, No. 3, 06.06.1978, p. 287-293.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Photochemical reaction between cyclohexyl isocyanide and π-cyclopentadienyldicarbonyltrimethylsilyliron(II)
AU - Chan, Tze Ming
AU - Connolly, John W.
AU - Hoff, Carl
AU - Millich, Frank
PY - 1978/6/6
Y1 - 1978/6/6
N2 - The photoreaction between C5H5Fe(CO)2Si(CH3)3 (I) and cyclohexyl isocyanide leads to the sequential replacement of both carbonyl groups by the isocyanide. Both the racemic monosubstituted product, C5H5Fe(CO)(C6H11NC)Si(CH3)3 (II) and the disubstituted product, C5H5Fe(C6H11NC)2Si(CH3)3 (III) have been isolated and characterized. Photoreaction between the disubstituted product III and C5H5Fe(CO)2Si(CH3)3 in a sealed tube gives the monosubstituted product, II. Thermal initiation of the above reactions failed. The disubstituted product III is stable under both the thermal and photochemical conditions used; thus, insertion of isocyanide into FeSi bond was observed not to occur.
AB - The photoreaction between C5H5Fe(CO)2Si(CH3)3 (I) and cyclohexyl isocyanide leads to the sequential replacement of both carbonyl groups by the isocyanide. Both the racemic monosubstituted product, C5H5Fe(CO)(C6H11NC)Si(CH3)3 (II) and the disubstituted product, C5H5Fe(C6H11NC)2Si(CH3)3 (III) have been isolated and characterized. Photoreaction between the disubstituted product III and C5H5Fe(CO)2Si(CH3)3 in a sealed tube gives the monosubstituted product, II. Thermal initiation of the above reactions failed. The disubstituted product III is stable under both the thermal and photochemical conditions used; thus, insertion of isocyanide into FeSi bond was observed not to occur.
UR - http://www.scopus.com/inward/record.url?scp=49349122862&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=49349122862&partnerID=8YFLogxK
U2 - 10.1016/S0022-328X(00)90647-8
DO - 10.1016/S0022-328X(00)90647-8
M3 - Article
AN - SCOPUS:49349122862
VL - 152
SP - 287
EP - 293
JO - Journal of Organometallic Chemistry
JF - Journal of Organometallic Chemistry
SN - 0022-328X
IS - 3
ER -