Photochemical generation and reactivity of carbenes within an organic cavitand and capsule: Photochemistry of adamantanediazirines

Shipra Gupta, Rajib Choudhury, Daniel Krois, Gerald Wagner, Udo H. Brinker, Vaidhyanathan Ramamurthy

Research output: Contribution to journalArticle

22 Citations (Scopus)

Abstract

Chemical behavior of carbenes (adamantylidenes) generated by photolysis of adamantanediazirines has been investigated while they were incarcerated within an organic container in water and on silica surfaces. Confined carbenes behave differently from the free ones, and their behavior is dictated by the nature and the structure of the host-guest complexes. The substituent present on the adamantyl skeleton controls the stoichiometry (1:1 or 2:2) and the orientation of guest molecules within the host.

Original languageEnglish
Pages (from-to)6074-6077
Number of pages4
JournalOrganic Letters
Volume13
Issue number22
DOIs
StatePublished - Nov 18 2011

Fingerprint

Photochemistry
Photochemical reactions
carbenes
capsules
photochemical reactions
Capsules
reactivity
Photolysis
containers
musculoskeletal system
Skeleton
Stoichiometry
Silicon Dioxide
Containers
photolysis
stoichiometry
silicon dioxide
Molecules
Water
water

ASJC Scopus subject areas

  • Organic Chemistry
  • Physical and Theoretical Chemistry
  • Biochemistry

Cite this

Photochemical generation and reactivity of carbenes within an organic cavitand and capsule : Photochemistry of adamantanediazirines. / Gupta, Shipra; Choudhury, Rajib; Krois, Daniel; Wagner, Gerald; Brinker, Udo H.; Ramamurthy, Vaidhyanathan.

In: Organic Letters, Vol. 13, No. 22, 18.11.2011, p. 6074-6077.

Research output: Contribution to journalArticle

Gupta, Shipra ; Choudhury, Rajib ; Krois, Daniel ; Wagner, Gerald ; Brinker, Udo H. ; Ramamurthy, Vaidhyanathan. / Photochemical generation and reactivity of carbenes within an organic cavitand and capsule : Photochemistry of adamantanediazirines. In: Organic Letters. 2011 ; Vol. 13, No. 22. pp. 6074-6077.
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