Perturbation-enhanced quenching of laser-excited CS A1π(ν = 0) by atomic oxygen

A. J. Hynes, J. H. Brophy

Research output: Contribution to journalArticlepeer-review

2 Scopus citations

Abstract

Quenching of CS A1Π(ν = 0) by O3 P is enhanced by perturbations due to á 3Σ+(ν = 10) and d3 Δ (ν = 4) The rotational-state dependence is linear in the singlet-triplet mixing coefficients and indicates an orientation-dependent interaction Symmetry correlations suggest that the perturbations promote formation of an attractive collision complex with quenching by intersystem crossing or chemical reaction.

Original languageEnglish (US)
Pages (from-to)52-56
Number of pages5
JournalChemical Physics Letters
Volume75
Issue number1
DOIs
StatePublished - Jan 1 1980
Externally publishedYes

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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