On the mathematical model of capillary electrophoresis

V. P. Andreev, E. E. Lisin

Research output: Contribution to journalArticle

34 Scopus citations

Abstract

The influence of the electroosmotic flow profile on the efficiency of capillary electrophoresis for a wide range of buffer concentrations and capillary diameters is studied. Thermal effects in the capillary, the finite size of solute molecules and their interactions with the capillary wall are also taken into consideration. The dependence of capillary electrophoresis efficiency and resolution on the zeta-potential values is investigated.

Original languageEnglish (US)
Pages (from-to)202-210
Number of pages9
JournalChromatographia
Volume37
Issue number3-4
DOIs
StatePublished - Aug 1 1993

Keywords

  • Electroosmosis
  • Electrophoresis
  • Mathematical model
  • Peak Broadening

ASJC Scopus subject areas

  • Analytical Chemistry
  • Clinical Biochemistry

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