Observations of ozone formation in power plant plumes and implications for ozone control strategies

T. B. Ryerson, M. Trainer, J. S. Holloway, D. D. Parrish, L. G. Huey, D. T. Sueper, G. J. Frost, S. G. Donnelly, S. Schauffler, E. L. Atlas, W. C. Kuster, P. D. Goldan, G. Hübler, J. F. Meagher, F. C. Fehsenfeld

Research output: Contribution to journalArticlepeer-review

221 Scopus citations

Abstract

Data taken in aircraft transects of emissions plumes from rural U.S. coal-fired power plants were used to confirm and quantify the nonlinear dependence of tropospheric ozone formation on plume NOx (NO plus NO2) concentration, which is determined by plant NOx emission rate and atmospheric dispersion. The ambient availability of reactive volatile organic compounds, principally biogenic isoprene, was also found to modulate ozone production rate and yield in these rural plumes. Differences of a factor of 2 or greater in plume ozone formation rates and yields as a function of NOx and volatile organic compound concentrations were consistently observed. These large differences suggest that consideration of power plant NOx emission rates and geographic locations in current and future U.S. ozone control strategies could substantially enhance the efficacy of NOx reductions from these sources.

Original languageEnglish (US)
Pages (from-to)719-723
Number of pages5
JournalScience
Volume292
Issue number5517
DOIs
StatePublished - Apr 27 2001
Externally publishedYes

ASJC Scopus subject areas

  • General

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