Norrish Type I and Type II Reactions of Ketones as Photochemical Probes of the Interior of Zeolites†,‡

V. Ramamurthy; D. R. Corbin; D. F. Eaton

doi:10.1021/jo00305a024

Norrish Type I and Type II Reactions of Ketones as Photochemical Probes of the Interior of Zeolites†,‡

V. Ramamurthy, D. R. Corbin, D. F. Eaton

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43 Scopus citations

Abstract

The Norrish type I and type II reactions of alkylbenzoin ethers, alkyldeoxybenzoins and α-alkyldibenzyl ketones included within the microporous structures of zeolites X and Y have been investigated. Product distributions varied significantly from that observed in benzene. In addition, it differed between various alkali-metal cation-exchanged samples. These variations are interpreted to result from the restriction offered by the zeolite micropores on the motions of the adsorbed organic molecule. Although this study is restricted to ketones, the knowledge gained is expected to be of general value.

Original language	English (US)
Pages (from-to)	5269-5278
Number of pages	10
Journal	Journal of Organic Chemistry
Volume	55
Issue number	18
DOIs	https://doi.org/10.1021/jo00305a024
State	Published - Aug 1990
Externally published	Yes

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Organic Chemistry

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title = "Norrish Type I and Type II Reactions of Ketones as Photochemical Probes of the Interior of Zeolites†,‡",

abstract = "The Norrish type I and type II reactions of alkylbenzoin ethers, alkyldeoxybenzoins and α-alkyldibenzyl ketones included within the microporous structures of zeolites X and Y have been investigated. Product distributions varied significantly from that observed in benzene. In addition, it differed between various alkali-metal cation-exchanged samples. These variations are interpreted to result from the restriction offered by the zeolite micropores on the motions of the adsorbed organic molecule. Although this study is restricted to ketones, the knowledge gained is expected to be of general value.",

author = "V. Ramamurthy and Corbin, {D. R.} and Eaton, {D. F.}",

year = "1990",

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language = "English (US)",

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AU - Corbin, D. R.

AU - Eaton, D. F.

PY - 1990/8

Y1 - 1990/8

N2 - The Norrish type I and type II reactions of alkylbenzoin ethers, alkyldeoxybenzoins and α-alkyldibenzyl ketones included within the microporous structures of zeolites X and Y have been investigated. Product distributions varied significantly from that observed in benzene. In addition, it differed between various alkali-metal cation-exchanged samples. These variations are interpreted to result from the restriction offered by the zeolite micropores on the motions of the adsorbed organic molecule. Although this study is restricted to ketones, the knowledge gained is expected to be of general value.

AB - The Norrish type I and type II reactions of alkylbenzoin ethers, alkyldeoxybenzoins and α-alkyldibenzyl ketones included within the microporous structures of zeolites X and Y have been investigated. Product distributions varied significantly from that observed in benzene. In addition, it differed between various alkali-metal cation-exchanged samples. These variations are interpreted to result from the restriction offered by the zeolite micropores on the motions of the adsorbed organic molecule. Although this study is restricted to ketones, the knowledge gained is expected to be of general value.

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Norrish Type I and Type II Reactions of Ketones as Photochemical Probes of the Interior of Zeolites†,‡

Abstract

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