Norrish Type I and Type II Reactions of Ketones as Photochemical Probes of the Interior of Zeolites†,‡

V. Ramamurthy; D. R. Corbin; D. F. Eaton

doi:10.1021/jo00305a024

Norrish Type I and Type II Reactions of Ketones as Photochemical Probes of the Interior of Zeolites†,‡

V. Ramamurthy, D. R. Corbin, D. F. Eaton

Research output: Contribution to journal › Article › peer-review

43 Scopus citations

Abstract

The Norrish type I and type II reactions of alkylbenzoin ethers, alkyldeoxybenzoins and α-alkyldibenzyl ketones included within the microporous structures of zeolites X and Y have been investigated. Product distributions varied significantly from that observed in benzene. In addition, it differed between various alkali-metal cation-exchanged samples. These variations are interpreted to result from the restriction offered by the zeolite micropores on the motions of the adsorbed organic molecule. Although this study is restricted to ketones, the knowledge gained is expected to be of general value.

Original language	English (US)
Pages (from-to)	5269-5278
Number of pages	10
Journal	Journal of Organic Chemistry
Volume	55
Issue number	18
DOIs	https://doi.org/10.1021/jo00305a024
State	Published - Aug 1990
Externally published	Yes

ASJC Scopus subject areas

Organic Chemistry

Access to Document

10.1021/jo00305a024

Fingerprint Dive into the research topics of 'Norrish Type I and Type II Reactions of Ketones as Photochemical Probes of the Interior of Zeolites†,‡'. Together they form a unique fingerprint.

Cite this

@article{53ad608717ba4d6f910786429244ef52,

title = "Norrish Type I and Type II Reactions of Ketones as Photochemical Probes of the Interior of Zeolites†,‡",

abstract = "The Norrish type I and type II reactions of alkylbenzoin ethers, alkyldeoxybenzoins and α-alkyldibenzyl ketones included within the microporous structures of zeolites X and Y have been investigated. Product distributions varied significantly from that observed in benzene. In addition, it differed between various alkali-metal cation-exchanged samples. These variations are interpreted to result from the restriction offered by the zeolite micropores on the motions of the adsorbed organic molecule. Although this study is restricted to ketones, the knowledge gained is expected to be of general value.",

author = "V. Ramamurthy and Corbin, {D. R.} and Eaton, {D. F.}",

year = "1990",

month = aug,

doi = "10.1021/jo00305a024",

language = "English (US)",

volume = "55",

pages = "5269--5278",

journal = "Journal of Organic Chemistry",

issn = "0022-3263",

publisher = "American Chemical Society",

number = "18",

}

TY - JOUR

T1 - Norrish Type I and Type II Reactions of Ketones as Photochemical Probes of the Interior of Zeolites†,‡

AU - Ramamurthy, V.

AU - Corbin, D. R.

AU - Eaton, D. F.

PY - 1990/8

Y1 - 1990/8

N2 - The Norrish type I and type II reactions of alkylbenzoin ethers, alkyldeoxybenzoins and α-alkyldibenzyl ketones included within the microporous structures of zeolites X and Y have been investigated. Product distributions varied significantly from that observed in benzene. In addition, it differed between various alkali-metal cation-exchanged samples. These variations are interpreted to result from the restriction offered by the zeolite micropores on the motions of the adsorbed organic molecule. Although this study is restricted to ketones, the knowledge gained is expected to be of general value.

AB - The Norrish type I and type II reactions of alkylbenzoin ethers, alkyldeoxybenzoins and α-alkyldibenzyl ketones included within the microporous structures of zeolites X and Y have been investigated. Product distributions varied significantly from that observed in benzene. In addition, it differed between various alkali-metal cation-exchanged samples. These variations are interpreted to result from the restriction offered by the zeolite micropores on the motions of the adsorbed organic molecule. Although this study is restricted to ketones, the knowledge gained is expected to be of general value.

UR - http://www.scopus.com/inward/record.url?scp=0000633024&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0000633024&partnerID=8YFLogxK

U2 - 10.1021/jo00305a024

DO - 10.1021/jo00305a024

M3 - Article

AN - SCOPUS:0000633024

VL - 55

SP - 5269

EP - 5278

JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

SN - 0022-3263

IS - 18

ER -

Norrish Type I and Type II Reactions of Ketones as Photochemical Probes of the Interior of Zeolites†,‡

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Cite this