Abstract
The Norrish type I and type II reactions of alkylbenzoin ethers, alkyldeoxybenzoins and α-alkyldibenzyl ketones included within the microporous structures of zeolites X and Y have been investigated. Product distributions varied significantly from that observed in benzene. In addition, it differed between various alkali-metal cation-exchanged samples. These variations are interpreted to result from the restriction offered by the zeolite micropores on the motions of the adsorbed organic molecule. Although this study is restricted to ketones, the knowledge gained is expected to be of general value.
| Original language | English |
|---|---|
| Pages (from-to) | 5269-5278 |
| Number of pages | 10 |
| Journal | Journal of Organic Chemistry |
| Volume | 55 |
| Issue number | 18 |
| State | Published - Dec 1 1990 |
| Externally published | Yes |
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ASJC Scopus subject areas
- Organic Chemistry
Cite this
Norrish type I and Type II reactions of ketones as photochemical probes of the interior of zeolites. / Ramamurthy, Vaidhyanathan; Corbin, D. R.; Eaton, D. F.
In: Journal of Organic Chemistry, Vol. 55, No. 18, 01.12.1990, p. 5269-5278.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Norrish type I and Type II reactions of ketones as photochemical probes of the interior of zeolites
AU - Ramamurthy, Vaidhyanathan
AU - Corbin, D. R.
AU - Eaton, D. F.
PY - 1990/12/1
Y1 - 1990/12/1
N2 - The Norrish type I and type II reactions of alkylbenzoin ethers, alkyldeoxybenzoins and α-alkyldibenzyl ketones included within the microporous structures of zeolites X and Y have been investigated. Product distributions varied significantly from that observed in benzene. In addition, it differed between various alkali-metal cation-exchanged samples. These variations are interpreted to result from the restriction offered by the zeolite micropores on the motions of the adsorbed organic molecule. Although this study is restricted to ketones, the knowledge gained is expected to be of general value.
AB - The Norrish type I and type II reactions of alkylbenzoin ethers, alkyldeoxybenzoins and α-alkyldibenzyl ketones included within the microporous structures of zeolites X and Y have been investigated. Product distributions varied significantly from that observed in benzene. In addition, it differed between various alkali-metal cation-exchanged samples. These variations are interpreted to result from the restriction offered by the zeolite micropores on the motions of the adsorbed organic molecule. Although this study is restricted to ketones, the knowledge gained is expected to be of general value.
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UR - http://www.scopus.com/inward/citedby.url?scp=0000633024&partnerID=8YFLogxK
M3 - Article
VL - 55
SP - 5269
EP - 5278
JO - Journal of Organic Chemistry
JF - Journal of Organic Chemistry
SN - 0022-3263
IS - 18
ER -