Abstract
The hydrolysis reaction (Chemical Equation Presented) has been studied. For R = CN, kh = 1050 ± 60 M-1 s-1, ΔH‡ = 13.6 ± 0.5 kcal mol-1, ΔS‡ = 1.0 ± 2 eu at 25°C, and I = 1.0 M (LiClO4). For R = CONH2, kh = (5.8 ± 0.5) × 106 M-1 s-1, ΔH‡ = 21.3 ± 0.5 kcal mol-1, ΔS‡ = 44 ± 2 eu at 25°C, and I = 1.0 M (LiClO4). The unusual kinetic parameters for the latter complex are attributed to neighboring-group participation by the amide group.
Original language | English (US) |
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Pages (from-to) | 4159-4163 |
Number of pages | 5 |
Journal | Inorganic Chemistry |
Volume | 20 |
Issue number | 12 |
DOIs | |
State | Published - Dec 1981 |
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Inorganic Chemistry