Multiple reactions of triphenylstannane with Ru5(CO)12 (C6H6)(μ5-C) yield bimetallic clusters with unusually large numbers of tin ligands

Richard D. Adams; Burjor Captain; Wei Fu; Mark D. Smith

doi:10.1021/ic011321u

Multiple reactions of triphenylstannane with Ru₅(CO)₁₂ (C₆H₆)(μ₅-C) yield bimetallic clusters with unusually large numbers of tin ligands

Richard D. Adams, Burjor Captain, Wei Fu, Mark D. Smith

Research output: Contribution to journal › Article › peer-review

45 Scopus citations

Abstract

The cluster complex Ru₅(CO)₁₂ (C₆H₆)(μ₅-C), 1, undergoes multiple addition reactions with Ph₃SnH to yield two new bimetallic cluster complexes: Ru₅(CO)₈ (μ-SnPh₂)₄ (C₆H₆)(μ₅-C), 2, 2% yield, and Ru₅-(CO)₇(μ-SnPh₂)₄ (SnPh₃)(C₆H₆)(μ₅-C)(μ-H), 3, 26% yield, containing four and five tin ligands, respectively. Both compounds consist of a square pyramidal Ru₅ cluster with an interstitial carbido ligand and bridging SnPh₂ groups located across each of the four edges of the base of the Ru₅ square pyramid. Compound 3 contains an additional SnPh₃ group terminally coordinated to one of the ruthenium atoms in the square base.

Original language	English (US)
Pages (from-to)	2302-2303
Number of pages	2
Journal	Inorganic Chemistry
Volume	41
Issue number	9
DOIs	https://doi.org/10.1021/ic011321u
State	Published - May 6 2002
Externally published	Yes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry

Access to Document

10.1021/ic011321u

Fingerprint Dive into the research topics of 'Multiple reactions of triphenylstannane with Ru5(CO)12 (C6H6)(μ5-C) yield bimetallic clusters with unusually large numbers of tin ligands'. Together they form a unique fingerprint.

Cite this

@article{038a414adb604b89b585c3601347108c,

title = "Multiple reactions of triphenylstannane with Ru5(CO)12 (C6H6)(μ5-C) yield bimetallic clusters with unusually large numbers of tin ligands",

abstract = "The cluster complex Ru5(CO)12 (C6H6)(μ5-C), 1, undergoes multiple addition reactions with Ph3SnH to yield two new bimetallic cluster complexes: Ru5(CO)8 (μ-SnPh2)4 (C6H6)(μ5-C), 2, 2% yield, and Ru5-(CO)7(μ-SnPh2)4 (SnPh3)(C6H6)(μ5-C)(μ-H), 3, 26% yield, containing four and five tin ligands, respectively. Both compounds consist of a square pyramidal Ru5 cluster with an interstitial carbido ligand and bridging SnPh2 groups located across each of the four edges of the base of the Ru5 square pyramid. Compound 3 contains an additional SnPh3 group terminally coordinated to one of the ruthenium atoms in the square base.",

author = "Adams, {Richard D.} and Burjor Captain and Wei Fu and Smith, {Mark D.}",

year = "2002",

month = may,

day = "6",

doi = "10.1021/ic011321u",

language = "English (US)",

volume = "41",

pages = "2302--2303",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "9",

}

TY - JOUR

T1 - Multiple reactions of triphenylstannane with Ru5(CO)12 (C6H6)(μ5-C) yield bimetallic clusters with unusually large numbers of tin ligands

AU - Adams, Richard D.

AU - Captain, Burjor

AU - Fu, Wei

AU - Smith, Mark D.

PY - 2002/5/6

Y1 - 2002/5/6

N2 - The cluster complex Ru5(CO)12 (C6H6)(μ5-C), 1, undergoes multiple addition reactions with Ph3SnH to yield two new bimetallic cluster complexes: Ru5(CO)8 (μ-SnPh2)4 (C6H6)(μ5-C), 2, 2% yield, and Ru5-(CO)7(μ-SnPh2)4 (SnPh3)(C6H6)(μ5-C)(μ-H), 3, 26% yield, containing four and five tin ligands, respectively. Both compounds consist of a square pyramidal Ru5 cluster with an interstitial carbido ligand and bridging SnPh2 groups located across each of the four edges of the base of the Ru5 square pyramid. Compound 3 contains an additional SnPh3 group terminally coordinated to one of the ruthenium atoms in the square base.

AB - The cluster complex Ru5(CO)12 (C6H6)(μ5-C), 1, undergoes multiple addition reactions with Ph3SnH to yield two new bimetallic cluster complexes: Ru5(CO)8 (μ-SnPh2)4 (C6H6)(μ5-C), 2, 2% yield, and Ru5-(CO)7(μ-SnPh2)4 (SnPh3)(C6H6)(μ5-C)(μ-H), 3, 26% yield, containing four and five tin ligands, respectively. Both compounds consist of a square pyramidal Ru5 cluster with an interstitial carbido ligand and bridging SnPh2 groups located across each of the four edges of the base of the Ru5 square pyramid. Compound 3 contains an additional SnPh3 group terminally coordinated to one of the ruthenium atoms in the square base.

UR - http://www.scopus.com/inward/record.url?scp=0037029909&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0037029909&partnerID=8YFLogxK

U2 - 10.1021/ic011321u

DO - 10.1021/ic011321u

M3 - Article

C2 - 11978087

AN - SCOPUS:0037029909

VL - 41

SP - 2302

EP - 2303

JO - Inorganic Chemistry

JF - Inorganic Chemistry

SN - 0020-1669

IS - 9

ER -