Abstract
Following the homodoping strategy, which consists of mixing two amphiphilic derivatives of the same electroactive compound, one in the neutral state whereas the other is ionic, we have carefully investigated the mixed monolayers by in situ experiments. Using surface pressure isotherms together with surface potential technique but also visible-UV and IR spectroscopies we have characterized the molecular organization. We have shown for the first time that for a given range of mixtures mixed valence clusters likely to be TCNQ-type dimers are formed at the air-water interface.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 187-192 |
| Number of pages | 6 |
| Journal | Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals |
| Volume | 234 |
| Issue number | 1 |
| DOIs | |
| State | Published - 1993 |
| Externally published | Yes |
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ASJC Scopus subject areas
- Chemistry(all)
- Materials Science(all)
- Condensed Matter Physics
Cite this
Molecular organization of mixed monolayers (C18S)2 dithiolium-tcnq : Dodecyl-tcnq at the air-water interface. / Tian, Ke; Munger, G.; Leblanc, Roger; Fichet, O.; Desbat, B.; Delhaes, R.
In: Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals, Vol. 234, No. 1, 1993, p. 187-192.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Molecular organization of mixed monolayers (C18S)2 dithiolium-tcnq
T2 - Dodecyl-tcnq at the air-water interface
AU - Tian, Ke
AU - Munger, G.
AU - Leblanc, Roger
AU - Fichet, O.
AU - Desbat, B.
AU - Delhaes, R.
PY - 1993
Y1 - 1993
N2 - Following the homodoping strategy, which consists of mixing two amphiphilic derivatives of the same electroactive compound, one in the neutral state whereas the other is ionic, we have carefully investigated the mixed monolayers by in situ experiments. Using surface pressure isotherms together with surface potential technique but also visible-UV and IR spectroscopies we have characterized the molecular organization. We have shown for the first time that for a given range of mixtures mixed valence clusters likely to be TCNQ-type dimers are formed at the air-water interface.
AB - Following the homodoping strategy, which consists of mixing two amphiphilic derivatives of the same electroactive compound, one in the neutral state whereas the other is ionic, we have carefully investigated the mixed monolayers by in situ experiments. Using surface pressure isotherms together with surface potential technique but also visible-UV and IR spectroscopies we have characterized the molecular organization. We have shown for the first time that for a given range of mixtures mixed valence clusters likely to be TCNQ-type dimers are formed at the air-water interface.
UR - http://www.scopus.com/inward/record.url?scp=84963421252&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84963421252&partnerID=8YFLogxK
U2 - 10.1080/10587259308042914
DO - 10.1080/10587259308042914
M3 - Article
AN - SCOPUS:84963421252
VL - 234
SP - 187
EP - 192
JO - Molecular Crystals and Liquid Crystals
JF - Molecular Crystals and Liquid Crystals
SN - 1542-1406
IS - 1
ER -