Molecular organization of mixed monolayers (C18S)2 dithiolium-tcnq: Dodecyl-tcnq at the air-water interface

Ke Tian; G. Munger; Roger Leblanc; O. Fichet; B. Desbat; R. Delhaes

doi:10.1080/10587259308042914

Molecular organization of mixed monolayers (C₁₈S)₂ dithiolium-tcnq: Dodecyl-tcnq at the air-water interface

Ke Tian, G. Munger, Roger Leblanc, O. Fichet, B. Desbat, R. Delhaes

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

Following the homodoping strategy, which consists of mixing two amphiphilic derivatives of the same electroactive compound, one in the neutral state whereas the other is ionic, we have carefully investigated the mixed monolayers by in situ experiments. Using surface pressure isotherms together with surface potential technique but also visible-UV and IR spectroscopies we have characterized the molecular organization. We have shown for the first time that for a given range of mixtures mixed valence clusters likely to be TCNQ-type dimers are formed at the air-water interface.

Original language	English (US)
Pages (from-to)	187-192
Number of pages	6
Journal	Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals
Volume	234
Issue number	1
DOIs	https://doi.org/10.1080/10587259308042914
State	Published - 1993
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

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Molecular organization of mixed monolayers (C₁₈S)₂ dithiolium-tcnq : Dodecyl-tcnq at the air-water interface. / Tian, Ke; Munger, G.; Leblanc, Roger; Fichet, O.; Desbat, B.; Delhaes, R.

In: Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals, Vol. 234, No. 1, 1993, p. 187-192.

Research output: Contribution to journal › Article › peer-review

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