Modification of photochemical reactivity by zeolites: Selective photorearrangement of α-alkyldeoxybenzoins to p-alkylbenzophenones in the cavities of faujasites

D. R. Corbin, D. F. Eaton, Vaidhyanathan Ramamurthy

Research output: Contribution to journal › Article

19 Citations (Scopus)

Abstract

Photolysis of α-alkyldeoxybenzoins included in Li-X and Li-Y zeolites gave the corresponding rearranged p-alkylbenzophenones in near quantitative yields via the Norrish type α-cleavage process. Such a striking behavior contrasts their normal reactivity in solution.

Original languageEnglish
Pages (from-to)5384-5386
Number of pages3
JournalJournal of Organic Chemistry
Volume53
Issue number22
StatePublished - Dec 1 1988
Externally publishedYes

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Zeolites
Photolysis
faujasite

ASJC Scopus subject areas

  • Organic Chemistry

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Modification of photochemical reactivity by zeolites : Selective photorearrangement of α-alkyldeoxybenzoins to p-alkylbenzophenones in the cavities of faujasites. / Corbin, D. R.; Eaton, D. F.; Ramamurthy, Vaidhyanathan.

In: Journal of Organic Chemistry, Vol. 53, No. 22, 01.12.1988, p. 5384-5386.

Research output: Contribution to journal › Article

Corbin, DR, Eaton, DF & Ramamurthy, V 1988, 'Modification of photochemical reactivity by zeolites: Selective photorearrangement of α-alkyldeoxybenzoins to p-alkylbenzophenones in the cavities of faujasites', Journal of Organic Chemistry, vol. 53, no. 22, pp. 5384-5386.
Corbin DR, Eaton DF, Ramamurthy V. Modification of photochemical reactivity by zeolites: Selective photorearrangement of α-alkyldeoxybenzoins to p-alkylbenzophenones in the cavities of faujasites. Journal of Organic Chemistry. 1988 Dec 1;53(22):5384-5386.
Corbin, D. R. ; Eaton, D. F. ; Ramamurthy, Vaidhyanathan. / Modification of photochemical reactivity by zeolites : Selective photorearrangement of α-alkyldeoxybenzoins to p-alkylbenzophenones in the cavities of faujasites. In: Journal of Organic Chemistry. 1988 ; Vol. 53, No. 22. pp. 5384-5386.
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