Modification of Photochemical Reactivity by Zeolites: Selective Photorearrangement of α-Alkyldeoxybenzoins to p-Alkylbenzophenones in the Cavities of Faujasites

D. R. Corbin; D. F. Eaton; V. Ramamurthy

doi:10.1021/jo00257a043

Modification of Photochemical Reactivity by Zeolites: Selective Photorearrangement of α-Alkyldeoxybenzoins to p-Alkylbenzophenones in the Cavities of Faujasites

D. R. Corbin, D. F. Eaton, V. Ramamurthy

Research output: Contribution to journal › Article › peer-review

19 Scopus citations

Abstract

Photolysis of α-alkyldeoxybenzoins included in Li-X and Li-Y zeolites gave the corresponding rearranged p-alkylbenzophenones in near quantitative yields via the Norrish type α-cleavage process. Such a striking behavior contrasts their normal reactivity in solution.

Original language	English (US)
Pages (from-to)	5384-5386
Number of pages	3
Journal	Journal of Organic Chemistry
Volume	53
Issue number	22
DOIs	https://doi.org/10.1021/jo00257a043
State	Published - Oct 1 1988
Externally published	Yes

ASJC Scopus subject areas

Organic Chemistry

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title = "Modification of Photochemical Reactivity by Zeolites: Selective Photorearrangement of α-Alkyldeoxybenzoins to p-Alkylbenzophenones in the Cavities of Faujasites",

abstract = "Photolysis of α-alkyldeoxybenzoins included in Li-X and Li-Y zeolites gave the corresponding rearranged p-alkylbenzophenones in near quantitative yields via the Norrish type α-cleavage process. Such a striking behavior contrasts their normal reactivity in solution.",

author = "Corbin, {D. R.} and Eaton, {D. F.} and V. Ramamurthy",

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AU - Eaton, D. F.

AU - Ramamurthy, V.

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AB - Photolysis of α-alkyldeoxybenzoins included in Li-X and Li-Y zeolites gave the corresponding rearranged p-alkylbenzophenones in near quantitative yields via the Norrish type α-cleavage process. Such a striking behavior contrasts their normal reactivity in solution.

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