Modification of photochemical reactivity by zeolites: Selective photorearrangement of α-alkyldeoxybenzoins to p-alkylbenzophenones in the cavities of faujasites

D. R. Corbin, D. F. Eaton, Vaidhyanathan Ramamurthy

Research output: Contribution to journalArticle

19 Citations (Scopus)

Abstract

Photolysis of α-alkyldeoxybenzoins included in Li-X and Li-Y zeolites gave the corresponding rearranged p-alkylbenzophenones in near quantitative yields via the Norrish type α-cleavage process. Such a striking behavior contrasts their normal reactivity in solution.

Original languageEnglish
Pages (from-to)5384-5386
Number of pages3
JournalJournal of Organic Chemistry
Volume53
Issue number22
StatePublished - Dec 1 1988
Externally publishedYes

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Zeolites
Photolysis
faujasite

ASJC Scopus subject areas

  • Organic Chemistry

Cite this

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title = "Modification of photochemical reactivity by zeolites: Selective photorearrangement of α-alkyldeoxybenzoins to p-alkylbenzophenones in the cavities of faujasites",
abstract = "Photolysis of α-alkyldeoxybenzoins included in Li-X and Li-Y zeolites gave the corresponding rearranged p-alkylbenzophenones in near quantitative yields via the Norrish type α-cleavage process. Such a striking behavior contrasts their normal reactivity in solution.",
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AU - Eaton, D. F.

AU - Ramamurthy, Vaidhyanathan

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AB - Photolysis of α-alkyldeoxybenzoins included in Li-X and Li-Y zeolites gave the corresponding rearranged p-alkylbenzophenones in near quantitative yields via the Norrish type α-cleavage process. Such a striking behavior contrasts their normal reactivity in solution.

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