TY - JOUR
T1 - Modification of photochemical reactivity by zeolites
T2 - Consequences of rotational restriction on Norrish type II reaction of alkanophenones
AU - Ramamurthy, V.
AU - Corbin, D. R.
AU - Eaton, D. F.
PY - 1989/1/1
Y1 - 1989/1/1
N2 - The photolysis of several alkanophenones in monovalent cation exchanged faujasites and in pentasil zeolites, occured with expected γ-hydrogen abstraction and the ratio of the products derived differed; cyclobutanol formation was completely suppressed in pentasils, probably due to restruction of the rotational motion of the central σ bond present in the Norrish type II derived 1,4-diradical.
AB - The photolysis of several alkanophenones in monovalent cation exchanged faujasites and in pentasil zeolites, occured with expected γ-hydrogen abstraction and the ratio of the products derived differed; cyclobutanol formation was completely suppressed in pentasils, probably due to restruction of the rotational motion of the central σ bond present in the Norrish type II derived 1,4-diradical.
UR - http://www.scopus.com/inward/record.url?scp=37049079849&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=37049079849&partnerID=8YFLogxK
U2 - 10.1039/C39890001213
DO - 10.1039/C39890001213
M3 - Article
AN - SCOPUS:37049079849
SP - 1213
EP - 1214
JO - Journal of the Chemical Society
JF - Journal of the Chemical Society
SN - 0577-6171
IS - 17
ER -