Abstract
The photolysis of several alkanophenones in monovalent cation exchanged faujasites and in pentasil zeolites, occured with expected γ-hydrogen abstraction and the ratio of the products derived differed; cyclobutanol formation was completely suppressed in pentasils, probably due to restruction of the rotational motion of the central σ bond present in the Norrish type II derived 1,4-diradical.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 1213-1214 |
| Number of pages | 2 |
| Journal | Journal of the Chemical Society, Chemical Communications |
| Issue number | 17 |
| DOIs | |
| State | Published - Jan 1 1989 |
| Externally published | Yes |
ASJC Scopus subject areas
- Molecular Medicine
Fingerprint Dive into the research topics of 'Modification of photochemical reactivity by zeolites: Consequences of rotational restriction on Norrish type II reaction of alkanophenones'. Together they form a unique fingerprint.
Cite this
Ramamurthy, V., Corbin, D. R., & Eaton, D. F. (1989). Modification of photochemical reactivity by zeolites: Consequences of rotational restriction on Norrish type II reaction of alkanophenones. Journal of the Chemical Society, Chemical Communications, (17), 1213-1214. https://doi.org/10.1039/C39890001213