Abstract
The photolysis of several alkanophenones in monovalent cation exchanged faujasites and in pentasil zeolites, occured with expected γ-hydrogen abstraction and the ratio of the products derived differed; cyclobutanol formation was completely suppressed in pentasils, probably due to restruction of the rotational motion of the central σ bond present in the Norrish type II derived 1,4-diradical.
| Original language | English |
|---|---|
| Pages (from-to) | 1213-1214 |
| Number of pages | 2 |
| Journal | Journal of the Chemical Society, Chemical Communications |
| Issue number | 17 |
| DOIs | |
| State | Published - Dec 1 1989 |
| Externally published | Yes |
Fingerprint
ASJC Scopus subject areas
- Molecular Medicine
Cite this
Modification of photochemical reactivity by zeolites : Consequences of rotational restriction on Norrish type II reaction of alkanophenones. / Ramamurthy, Vaidhyanathan; Corbin, D. R.; Eaton, D. F.
In: Journal of the Chemical Society, Chemical Communications, No. 17, 01.12.1989, p. 1213-1214.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Modification of photochemical reactivity by zeolites
T2 - Consequences of rotational restriction on Norrish type II reaction of alkanophenones
AU - Ramamurthy, Vaidhyanathan
AU - Corbin, D. R.
AU - Eaton, D. F.
PY - 1989/12/1
Y1 - 1989/12/1
N2 - The photolysis of several alkanophenones in monovalent cation exchanged faujasites and in pentasil zeolites, occured with expected γ-hydrogen abstraction and the ratio of the products derived differed; cyclobutanol formation was completely suppressed in pentasils, probably due to restruction of the rotational motion of the central σ bond present in the Norrish type II derived 1,4-diradical.
AB - The photolysis of several alkanophenones in monovalent cation exchanged faujasites and in pentasil zeolites, occured with expected γ-hydrogen abstraction and the ratio of the products derived differed; cyclobutanol formation was completely suppressed in pentasils, probably due to restruction of the rotational motion of the central σ bond present in the Norrish type II derived 1,4-diradical.
UR - http://www.scopus.com/inward/record.url?scp=37049079849&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=37049079849&partnerID=8YFLogxK
U2 - 10.1039/C39890001213
DO - 10.1039/C39890001213
M3 - Article
SP - 1213
EP - 1214
JO - Journal of the Chemical Society
JF - Journal of the Chemical Society
SN - 0577-6171
IS - 17
ER -